Characterisation and partition of valuable metals from WEEE in weathered municipal solid waste incineration bottom ash, with a view to recovering

As the demand for critical and valuable metals increases due to industrial developments, especially in electronics and high-technology industries, the search for novel and sustainable sources grows in significance. Incinerated municipal solid waste (MSW) is a potential source of valuable metals, since a lot of waste from electrical and electronic equipment (WEEE) is not recycled properly and are is managed together with the refuse fraction of MSW, which is often landfilled or incinerated. Bottom Ash (BA) is the main by-product of incinerated MSW, which has been characterized to assess the potential recovery of valuable metals. The determination of the total amount of valuable metals (Ag, Al, Au, Be, Co, Cu, Ga, Ge, In, Ir, Li, Ni, Pd, Pt, Sb, Ta, and W) in seasonal samples of weather bottom ash (WBA) was performed by a total acid digestion followed by a chemical analysis. Besides, a sequential extraction procedure (SEP) is conducted to define their partition. The characterisation has shown that the content of valuable metals in the incineration WBA, which was highest in the 0–2 mm fraction was much lower than in concentrated ores commonly used as primary sources. Moreover, the SEP showed little potential for the valorisation of most of the metals, as they are embedded in or bound to a silicic matrix or sintered metal oxides, and so their extraction requires strong-acid digestion or a highly oxidizing environment. This work contributes to the use of residual sources as secondary resources and to the correct management of the end-of-life electrical and electronic equipment. © 2019 Elsevier LtdThis work was partially funded by the Spanish Government (BIA2017-83912-C2-1-R). The authors would like to thank the companies SIRUSA and VECSA for their financial support and for providing access to sampling sites. The authors would like to thank the regional Catalan authorities for the accreditation of the quality of the research group: DIOPMA (2017 SGR 118). Mr. Maldonado-Alameda thanks the Catalan authorities for his postgraduate grant (FI-DGR 2017).Peer reviewe