Impact of wildfires on subsurface volcanic environments: New insights into speleothem chemistry

11 páginas.- 7 figuras.- 1 tabla.- 73 referencias.- Supplementary data to this article can be found online a https://doi.org/10.1016/j.scitotenv.2019.134321Siliceous speleothems frequently reported in volcanic caves have been traditionally interpreted as resulting from basalt weathering combined with the activity of microbial communities. A characteristic feature in lava tubes from Hawaii, Azores and Canary Islands is the occurrence of black jelly-like speleothems. Here we describe the formation process of siliceous black speleothems found in a lava tube from La Palma, Canary Islands, Spain, based on mineralogy, microscopy, light stable isotopes, analytical pyrolysis, NMR spectroscopy and chemometric analyses. The data indicate that the black speleothems are composed of a hydrated gel matrix of amorphous aluminum silicate materials containing charred vegetation and thermally degraded resins from pines or triterpenoids from Erica arborea, characteristic of the overlying laurel forest. This is the first observation of a connection between fire and speleothem chemistry from volcanic caves. We conclude that wildfires and organic matter from the surface area overlying caves may play an important role in the formation of speleothems found in La Palma and demonstrate that siliceous speleothems are potential archives for past fires.A.Z. Miller acknowledges the support from the Marie Curie Intra-European Fellowship of the European Commission seventh Framework Fig. 6. Contour van Krevelen density plots displaying cumulative abundances of pyrolysis compounds identified in Table S2 for: A) Erica arboreabiomass, B) Andosol topsoil, C) Black jelly-like speleothem 1 (BS1), and D) Black jelly-like speleothem 2 (BS2).9A.Z. Miller et al. / Science of the Total Environment 698 (2020) 134321 Programme (grant PIEF-GA-2012-328689) and the CEECIND/01147/2017 contract funded by Fundação para a Ciência e a Tecnologia (Portugal). The authors acknowledge the Spanish Ministry of Economy and Competitiveness (project CGL2013-41674-P) and ERDF funds forfi-nancial support. The authors are grateful to the speleologist OctavioFernández (GE Tebexcorade–La Palma) for the assistance during thefield trip and photographic documentation in the lava tubes from LaPalma IslandPeer reviewe