A new family of organometallic compounds, organozirconium reagents, are shown to serve as suitable partners in cross-coupling reactions of (activated) secondary alkyl electrophiles. Thus, the first catalytic method for coupling secondary α-bromoketones with alkenylmetal reagents has been developed, specifically, a mild, versatile, and stereoconvergent carbon−carbon bond-forming process that generates potentially labile β,γ-unsaturated ketones with good enantioselectivity
The ability of two common protected forms of amines (carbamates and sulfonamides) to serve as direct...
I. Alkyl Electrophiles in Cross-Coupling Reactions An overview of challenges associated with th...
The ability of two common protected forms of amines (carbamates and sulfonamides) to serve as direct...
A new family of organometallic compounds, organozirconium reagents, are shown to serve as suitable p...
Nickel box : The first catalytic asymmetric method for cross‐coupling arylzinc reagents with α‐bromo...
With the aid of a chiral nickel catalyst, enantioselective γ- (and δ-) alkylations of carbonyl compo...
We have developed a nickel-catalyzed method for the asymmetric cross-coupling of secondary electroph...
BACKGROUND: The development of useful new methods for the construction of carbon-carbon bonds has ha...
The first asymmetric Kumada reactions of alkyl electrophiles are described, specifically, cross-coup...
BACKGROUND: The development of useful new methods for the construction of carbon-carbon bonds has ha...
Carbon–carbon bonds, including those between sp^3-hybridized carbon atoms (alkyl–alkyl bonds), typic...
Carbon–carbon bonds, including those between sp^3-hybridized carbon atoms (alkyl–alkyl bonds), typic...
The first method for the stereoconvergent cross-coupling of racemic α-halonitriles is described, spe...
The first method for the stereoconvergent cross-coupling of racemic α-halonitriles is described, spe...
Metal‐catalyzed enantioconvergent cross‐coupling reactions of alkyl electrophiles are emerging as a ...
The ability of two common protected forms of amines (carbamates and sulfonamides) to serve as direct...
I. Alkyl Electrophiles in Cross-Coupling Reactions An overview of challenges associated with th...
The ability of two common protected forms of amines (carbamates and sulfonamides) to serve as direct...
A new family of organometallic compounds, organozirconium reagents, are shown to serve as suitable p...
Nickel box : The first catalytic asymmetric method for cross‐coupling arylzinc reagents with α‐bromo...
With the aid of a chiral nickel catalyst, enantioselective γ- (and δ-) alkylations of carbonyl compo...
We have developed a nickel-catalyzed method for the asymmetric cross-coupling of secondary electroph...
BACKGROUND: The development of useful new methods for the construction of carbon-carbon bonds has ha...
The first asymmetric Kumada reactions of alkyl electrophiles are described, specifically, cross-coup...
BACKGROUND: The development of useful new methods for the construction of carbon-carbon bonds has ha...
Carbon–carbon bonds, including those between sp^3-hybridized carbon atoms (alkyl–alkyl bonds), typic...
Carbon–carbon bonds, including those between sp^3-hybridized carbon atoms (alkyl–alkyl bonds), typic...
The first method for the stereoconvergent cross-coupling of racemic α-halonitriles is described, spe...
The first method for the stereoconvergent cross-coupling of racemic α-halonitriles is described, spe...
Metal‐catalyzed enantioconvergent cross‐coupling reactions of alkyl electrophiles are emerging as a ...
The ability of two common protected forms of amines (carbamates and sulfonamides) to serve as direct...
I. Alkyl Electrophiles in Cross-Coupling Reactions An overview of challenges associated with th...
The ability of two common protected forms of amines (carbamates and sulfonamides) to serve as direct...