This feature review describes the development of catalytic [4+2] and [4+3] cycloadditions of allenes, as efficient and practical methodologies for assembling six and seven-membered cyclic systems. The different methodologies have been classified depending on the type of key reactive intermediate that was proposed in the catalytic cycleS
The reaction of electronically unbiased allenes with alkenyldiazo compounds in the presence of gold...
Allene-ene-allene (2 and 5) and allene-yne-allene (3 and 7) N-tosyl and O-linked substrates were sat...
Long sought after [4+2] cyclases have sprouted up in numerous biosynthetic pathways in recent years,...
The development of efficient reactions that enable the construction of multiple bonds and/or stereog...
The development of efficient reactions that enable the construction of multiple bonds and/or stereog...
Allenamides are electron deficient allenamine equivalents that can participate in a range of cycload...
This dissertation is a culmination of research projects that combine the utility of computational me...
Transition metal-catalyzed cyclization reactions involving allenes were demonstrated as useful metho...
The development of new chemical processes for the formation of carbon-carbon bonds is an important t...
This is the peer reviewed version of the following article: Faustino, H. , Alonso, I. , Mascareñas, ...
The chemistry of strained cyclic alkynes has undergone a renaissance over the past two decades. Howe...
The reaction of N-allenamides with alkenyldiazo compounds in the presence of gold catalysts provided...
The reaction of electronically unbiased allenes with alkenyldiazo compounds in the presence of gold...
Allene-(E)-ene-yne N-tosyl-tethered substrates 3 a–3 h were efficiently prepared and their rhodium-c...
Allenes are very important chemical reagents in organic synthesis. Due to their high reactivity, the...
The reaction of electronically unbiased allenes with alkenyldiazo compounds in the presence of gold...
Allene-ene-allene (2 and 5) and allene-yne-allene (3 and 7) N-tosyl and O-linked substrates were sat...
Long sought after [4+2] cyclases have sprouted up in numerous biosynthetic pathways in recent years,...
The development of efficient reactions that enable the construction of multiple bonds and/or stereog...
The development of efficient reactions that enable the construction of multiple bonds and/or stereog...
Allenamides are electron deficient allenamine equivalents that can participate in a range of cycload...
This dissertation is a culmination of research projects that combine the utility of computational me...
Transition metal-catalyzed cyclization reactions involving allenes were demonstrated as useful metho...
The development of new chemical processes for the formation of carbon-carbon bonds is an important t...
This is the peer reviewed version of the following article: Faustino, H. , Alonso, I. , Mascareñas, ...
The chemistry of strained cyclic alkynes has undergone a renaissance over the past two decades. Howe...
The reaction of N-allenamides with alkenyldiazo compounds in the presence of gold catalysts provided...
The reaction of electronically unbiased allenes with alkenyldiazo compounds in the presence of gold...
Allene-(E)-ene-yne N-tosyl-tethered substrates 3 a–3 h were efficiently prepared and their rhodium-c...
Allenes are very important chemical reagents in organic synthesis. Due to their high reactivity, the...
The reaction of electronically unbiased allenes with alkenyldiazo compounds in the presence of gold...
Allene-ene-allene (2 and 5) and allene-yne-allene (3 and 7) N-tosyl and O-linked substrates were sat...
Long sought after [4+2] cyclases have sprouted up in numerous biosynthetic pathways in recent years,...