Diastereoisomeric forms of ligand-bridged dimetallic diruthenium(II) and ruthenium(II)–osmium(II) species containing bidentate polypyridyl ligands\ud

Reitsma, David R.
Keene, F. Richard

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Publication date

January 1993

DOI

10.1039/dt9930002859

Publisher

Royal Society of Chemistry

Abstract

A new general synthetic route is reported for dinuclear species of the type [((L(subscript t)₂)RuL(subscript b)Ru(L(subscript t)')₂]⁴⁺ or [(L(subscript t))₂RuL(subscript b)Os(L(subscript t)')₂]⁴⁺(L(subscript t)' L(subscript t)'= bidentate polypyridyl ligands, L(subscript t)≠ L(subscript t)'; L(subscript b)= bridging ligand), together with the chromatographic separation and characterization of the diastereoisomeric pairs of the dimers

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Diastereoisomeric forms of ligand-bridged dimetallic diruthenium(II) and ruthenium(II)–osmium(II) species containing bidentate polypyridyl ligands\ud

Abstract

Extracted data

Diastereoisomeric forms of ligand-bridged dimetallic diruthenium(II) and ruthenium(II)–osmium(II) species containing bidentate polypyridyl ligands\ud

Abstract

Extracted data

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