ChemInform Abstract: Mechanistic and Computational Studies of Oxidatively‐Induced Aryl—CF 3 Bond‐Formation at Pd: Rational Design of Room Temperature Aryl Trifluoromethylation.

Selective Single C(sp3)–F Bond Cleavage in Trifluoromethylarenes: Merging Visible-Light Catalysis with Lewis Acid Activation

Kang Chen (285159)
Nele Berg (4637356)
Ruth Gschwind (4637359)
Burkhard König (1446421)

November 2017

The conversion of easily available trifluoromethylarenes into aryldifluoromethyl compounds, which ar...

Catalytic Cycle for Palladium-Catalyzed Decarbonylative Trifluoromethylation using Trifluoroacetic Esters as the CF3 Source

Ansis Maleckis (1773259)
Melanie S. Sanford (1246980)

May 2014

This paper demonstrates a catalytic cycle for Pd-catalyzed decarbonylative trifluoromethylation usin...

Room Temperature Aryl Trifluoromethylation via Copper- Mediated Oxidative Cross-Coupling

Buchwald, Stephen Leffler
Senecal, Todd D.
Parsons, Andrew

November 2010

A method for the room temperature copper-mediated trifluoromethylation of aryl and heteroaryl boroni...

ACCOUNT ▌2005 accountInvestigations into Transition-Metal-Catalyzed Arene Trifluoromethylation Reactions

Transition-metal-catalyzed Arene
Trifluoromethylation Reactionsyingda Ye
Melanie S. Sanford

September 2016

Abstract: Trifluoromethyl-substituted arenes and heteroarenes are widely prevalent in pharmaceutical...

Mechanistic and computational studies of oxidatively-induced aryl-CF3 bond formation at palladium

Gary, J. Brannon

January 2010

This article describes the rational design of 1st generation systems for oxidatively-induced Aryl– C...

Synthesis and Reactivity of Palladium Trifluorides and Fluorides Towards Aryl C-CF3 and C-F Bond Formation.

Ball, Nicholas Dewayne

January 2011

The installation of carbon–fluorine and carbon-trifluoromethyl bonds in organic compounds can have a...

The Palladium Mediated Aromatic-Trifluoromethylation Reactions

Zhang, Jia

January 2018

The importance and challenges of, different approaches to, as well as the latest progress in the fie...

Nickel and Palladium Catalyzed C−H Trifluoromethylation using Trifluoromethyliodide: Investigations into New Reactivity

Solomon, Nicholas S.D.
Bhadbhade, Mohan
Tian, Ruoming
Keaveney, Sinead T.

January 2022

Due to the prevalence of the trifluoromethyl group (CF3) in high-value organic compounds, there is a...

A Theoretical Study on Pd-catalyzed, Friedel-Crafts Intermolecular Acylation: Does Generated In Situ Aroyl Triflate Act as A Reactive Electrophile to Functionalize C–H Bond of Arenes?

Rong Chang
Ye Tian
Niu Li
Jin Bai
Huimin Yan
Wenjing Yang
Zhen Guo
Yanrong Li

February 2019

The mechanism of Pd-catalyzed, Friedel-Crafts intermolecular acylation of arenes to ketones was comp...

Palladium-Catalyzed Oxidative Aryltrifluoromethylation of Activated Alkenes at Room Temperature

Xin Mu (400082)
Tao Wu (16763)
Hao-yang Wang (1489636)
Yin-long Guo (1489630)
Guosheng Liu (843458)

January 2012

A palladium-catalyzed intramolecular oxidative aryltrifluoromethylation reaction of activated alkene...

Oxidative Trifluoromethylation and other Functionalization Reactions of Alkenes and Alkynes

Janson, Pär

January 2014

This thesis concerns the use of various potent oxidants in organic synthesis. The main focus is dire...

Oxidative Trifluoromethylation and other Functionalization Reactions of Alkenes and Alkynes

Janson, Pär

January 2014

This thesis concerns the use of various potent oxidants in organic synthesis. The main focus is dire...

Investigations into Transition Metal Catalyzed/Mediated Arene Trifluoromethylation and Fluorination Reactions

Ye, Yingda

January 2013

Aryl–CF3 and aryl–F motifs are widely prevalent in pharmaceuticals and agrochemicals. As a result, t...

Exploring the synthetic utility of HFO-1234yf

MURRAY, BEN,JAMES

January 2021

The trifluoromethyl group is a common motif in pharmaceuticals, agrochemicals and organic materials ...

Investigations into Transition Metal Catalyzed/Mediated Arene Trifluoromethylation and Fluorination Reactions

Ye, Yingda

January 2013

Aryl–CF3 and aryl–F motifs are widely prevalent in pharmaceuticals and agrochemicals. As a result, t...

Selective Single C(sp3)–F Bond Cleavage in Trifluoromethylarenes: Merging Visible-Light Catalysis with Lewis Acid Activation

Kang Chen (285159)
Nele Berg (4637356)
Ruth Gschwind (4637359)
Burkhard König (1446421)

November 2017

The conversion of easily available trifluoromethylarenes into aryldifluoromethyl compounds, which ar...

Catalytic Cycle for Palladium-Catalyzed Decarbonylative Trifluoromethylation using Trifluoroacetic Esters as the CF3 Source

Ansis Maleckis (1773259)
Melanie S. Sanford (1246980)

May 2014

This paper demonstrates a catalytic cycle for Pd-catalyzed decarbonylative trifluoromethylation usin...

Room Temperature Aryl Trifluoromethylation via Copper- Mediated Oxidative Cross-Coupling

Buchwald, Stephen Leffler
Senecal, Todd D.
Parsons, Andrew

November 2010

A method for the room temperature copper-mediated trifluoromethylation of aryl and heteroaryl boroni...

ACCOUNT ▌2005 accountInvestigations into Transition-Metal-Catalyzed Arene Trifluoromethylation Reactions

Transition-metal-catalyzed Arene
Trifluoromethylation Reactionsyingda Ye
Melanie S. Sanford

September 2016

Abstract: Trifluoromethyl-substituted arenes and heteroarenes are widely prevalent in pharmaceutical...

Mechanistic and computational studies of oxidatively-induced aryl-CF3 bond formation at palladium

Gary, J. Brannon

January 2010

This article describes the rational design of 1st generation systems for oxidatively-induced Aryl– C...

Synthesis and Reactivity of Palladium Trifluorides and Fluorides Towards Aryl C-CF3 and C-F Bond Formation.

Ball, Nicholas Dewayne

January 2011

The installation of carbon–fluorine and carbon-trifluoromethyl bonds in organic compounds can have a...

The Palladium Mediated Aromatic-Trifluoromethylation Reactions

Zhang, Jia

January 2018

The importance and challenges of, different approaches to, as well as the latest progress in the fie...

Nickel and Palladium Catalyzed C−H Trifluoromethylation using Trifluoromethyliodide: Investigations into New Reactivity

Solomon, Nicholas S.D.
Bhadbhade, Mohan
Tian, Ruoming
Keaveney, Sinead T.

January 2022

Due to the prevalence of the trifluoromethyl group (CF3) in high-value organic compounds, there is a...

A Theoretical Study on Pd-catalyzed, Friedel-Crafts Intermolecular Acylation: Does Generated In Situ Aroyl Triflate Act as A Reactive Electrophile to Functionalize C–H Bond of Arenes?

Rong Chang
Ye Tian
Niu Li
Jin Bai
Huimin Yan
Wenjing Yang
Zhen Guo
Yanrong Li

February 2019

The mechanism of Pd-catalyzed, Friedel-Crafts intermolecular acylation of arenes to ketones was comp...

Palladium-Catalyzed Oxidative Aryltrifluoromethylation of Activated Alkenes at Room Temperature

Xin Mu (400082)
Tao Wu (16763)
Hao-yang Wang (1489636)
Yin-long Guo (1489630)
Guosheng Liu (843458)

January 2012

A palladium-catalyzed intramolecular oxidative aryltrifluoromethylation reaction of activated alkene...

Oxidative Trifluoromethylation and other Functionalization Reactions of Alkenes and Alkynes

Janson, Pär

January 2014

This thesis concerns the use of various potent oxidants in organic synthesis. The main focus is dire...

Oxidative Trifluoromethylation and other Functionalization Reactions of Alkenes and Alkynes

Janson, Pär

January 2014

This thesis concerns the use of various potent oxidants in organic synthesis. The main focus is dire...

Investigations into Transition Metal Catalyzed/Mediated Arene Trifluoromethylation and Fluorination Reactions

Ye, Yingda

January 2013

Aryl–CF3 and aryl–F motifs are widely prevalent in pharmaceuticals and agrochemicals. As a result, t...

Exploring the synthetic utility of HFO-1234yf

MURRAY, BEN,JAMES

January 2021

The trifluoromethyl group is a common motif in pharmaceuticals, agrochemicals and organic materials ...

Investigations into Transition Metal Catalyzed/Mediated Arene Trifluoromethylation and Fluorination Reactions

Ye, Yingda

January 2013

Aryl–CF3 and aryl–F motifs are widely prevalent in pharmaceuticals and agrochemicals. As a result, t...

Selective Single C(sp3)–F Bond Cleavage in Trifluoromethylarenes: Merging Visible-Light Catalysis with Lewis Acid Activation

Kang Chen (285159)
Nele Berg (4637356)
Ruth Gschwind (4637359)
Burkhard König (1446421)

November 2017

The conversion of easily available trifluoromethylarenes into aryldifluoromethyl compounds, which ar...

Catalytic Cycle for Palladium-Catalyzed Decarbonylative Trifluoromethylation using Trifluoroacetic Esters as the CF3 Source

Ansis Maleckis (1773259)
Melanie S. Sanford (1246980)

May 2014

This paper demonstrates a catalytic cycle for Pd-catalyzed decarbonylative trifluoromethylation usin...

Room Temperature Aryl Trifluoromethylation via Copper- Mediated Oxidative Cross-Coupling

Buchwald, Stephen Leffler
Senecal, Todd D.
Parsons, Andrew

November 2010

A method for the room temperature copper-mediated trifluoromethylation of aryl and heteroaryl boroni...

ChemInform Abstract: Mechanistic and Computational Studies of Oxidatively‐Induced Aryl—CF 3 Bond‐Formation at Pd: Rational Design of Room Temperature Aryl Trifluoromethylation.

Abstract

Extracted data

ChemInform Abstract: Mechanistic and Computational Studies of Oxidatively‐Induced Aryl—CF 3 Bond‐Formation at Pd: Rational Design of Room Temperature Aryl Trifluoromethylation.

Abstract

Extracted data

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