Thermochromic and Photoresponsive Cyanometalate Fe/Co Squares: Toward Control of the Electron Transfer Temperature
- Zhang, Yuan-Zhu
- Philip, Ferko
- Siretanu, Diana
- Ababei, Rodica
- P. Rath, Nigam
- Clérac, Rodolphe
- Mathonière, Corine
- Holmes, Stephen M.
Publication date
October 2014
DOI Publisher
American Chemical Society (ACS) ISSN
0002-7863 Citation count (estimate)
43Abstract
International audienceTwo structurally related and photoresponsive cyanide-bridged Fe/Co square complexes, {Fe2Co2}, are reported: {[(TpMe)Fe(CN)3]2[Co(bpy)2]2[(TpMe)Fe- (CN)3]2}·12H2O (2) and {[(TpMe)Fe(CN)3]2[Co-(bpy)2]2[BPh4]2}·6MeCN (3), where TpMe and bpy are hydridotris(3-methylpyrazol-1-yl)borate and 2,2′-bipyridine, respectively....
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