International audienceLet G be a connected Lie group and g its Lie algebra. We denote by ∇0 the torsion free bi-invariant linear connection on G given by , for any left invariant vector fields X,Y. A Poisson structure on g is a commutative and associative product on g for which adu is a derivation, for any u∈g. A torsion free bi-invariant linear connections on G which have the same curvature as ∇0 are called special. We show that there is a bijection between the space of special connections on G and the space of Poisson structures on g. We compute the holonomy Lie algebra of a special connection and we show that the Poisson structures associated to special connections which have the same holonomy Lie algebra as ∇0 possess interestin...