Immobilization of an Anthracene-Tagged Ruthenium Complex on a 2,4,7-Trinitrofluoren-9-one-Grafted Silica: Efficiency and Recyclability in Olefin Metathesis Reactions
- Nasrallah, Houssein
- Pagnoux, Anastassiya
- Didier, Dorian
- Magnier, Caroline
- Toupet, Loic
- Guillot, Régis
- Crévisy, Christophe
- Mauduit, Marc
- Schulz, Emmanuelle
Publication date
December 2014
DOI Publisher
Wiley ISSN
1434-193X Citation count (estimate)
5Abstract
International audienceAn anthracene group was linked to the N-heterocyclic carbene moiety of a M71-SIPr-type Ru complex. The tagged complex thus obtained was immobilized by charge-transfer interactions to a 2,4,7-trinitrofluoren-9-one-grafted passivated silica. The immobilized complex proved to be an efficient olefin metathesis catalyst and was reused five times in a multisubstrate olefin metathesis procedure
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