The transition metal chalcogenides, M2P2S6 (M = divalent transition metal cation), are lamellar materials that undergo an unusual cation exchange process when their crystals are placed in contact with a solution of a transition metal salt. EPR spectroscopy has been used to examine the exchange of paramagnetic Co2+ for Cd2+ in diamagnetic Cd2P2S6. It has been possible to study the uptake of ions by the lamellar lattice and to examine the cation coordination environment through its effect on the parameters of the spin-Hamiltonian. In order to extract details of the Co2+ coordination from the observed EPR spectra, theoretical values of the g-value have been computed as a function of several crystal field parameters. The results for Co2+ are co...
Exposure of diamagnetic transition metal carbonyls and cyanides either as the pure compounds or as d...
The electron spin resonance (ESR) spectra of Eu2 +(4 f7, S = frac(7, 2)) in LaB6 single crystal show...
Detailed ESR investigations of Mn2+ substituting for Ca2+ in Ca2Sr(C2H5COO)6, (DSP) and Ca2Pb(C2H5CO...
Cd2P2S6 crystallizes in a layered structure which is readily intercalated with a variety of Lewis ba...
The lamellar transition metal Chalocogeno-Phosphates (M2P2S6) form an important family of two-dimens...
Transition metal chalcogenophosphates with the formula M2P2X6 (where M is a divalent transition meta...
The Q-band and X-band ESR spectra of Mn2+ in the layered compound Cd2P2Se6 are reported. The Mn2+ is...
Cd2P2S6 exhibits a layered crystal structure that may be intercalated with metallocenes. The ESR spe...
The transition metal phosphorus chalcogenides (M(,2)P(,2)X(,6), where M is a divalent transition met...
The transition metal chalcogenophosphates (MPS(,3)) crystallize in a layered structure where adjacen...
Properties of CdIn₂S₄ have been studied using EPR. The temperature dependence of the hyperfine inte...
CoII and CuII ions are two paramagnetic transition metal ions showing different relaxation rates (ν)...
The principles and experimental techniques of electron spin resonance (esr) are outlined in the earl...
ESR investigations on exchange coupled pairs of Cu ions in single crystals of Cu(dtc)2, isomorphousl...
Deuterium NMR spectra of the intercalation complexes of lamellar Cd2P2S6 with various deuterated pyr...
Exposure of diamagnetic transition metal carbonyls and cyanides either as the pure compounds or as d...
The electron spin resonance (ESR) spectra of Eu2 +(4 f7, S = frac(7, 2)) in LaB6 single crystal show...
Detailed ESR investigations of Mn2+ substituting for Ca2+ in Ca2Sr(C2H5COO)6, (DSP) and Ca2Pb(C2H5CO...
Cd2P2S6 crystallizes in a layered structure which is readily intercalated with a variety of Lewis ba...
The lamellar transition metal Chalocogeno-Phosphates (M2P2S6) form an important family of two-dimens...
Transition metal chalcogenophosphates with the formula M2P2X6 (where M is a divalent transition meta...
The Q-band and X-band ESR spectra of Mn2+ in the layered compound Cd2P2Se6 are reported. The Mn2+ is...
Cd2P2S6 exhibits a layered crystal structure that may be intercalated with metallocenes. The ESR spe...
The transition metal phosphorus chalcogenides (M(,2)P(,2)X(,6), where M is a divalent transition met...
The transition metal chalcogenophosphates (MPS(,3)) crystallize in a layered structure where adjacen...
Properties of CdIn₂S₄ have been studied using EPR. The temperature dependence of the hyperfine inte...
CoII and CuII ions are two paramagnetic transition metal ions showing different relaxation rates (ν)...
The principles and experimental techniques of electron spin resonance (esr) are outlined in the earl...
ESR investigations on exchange coupled pairs of Cu ions in single crystals of Cu(dtc)2, isomorphousl...
Deuterium NMR spectra of the intercalation complexes of lamellar Cd2P2S6 with various deuterated pyr...
Exposure of diamagnetic transition metal carbonyls and cyanides either as the pure compounds or as d...
The electron spin resonance (ESR) spectra of Eu2 +(4 f7, S = frac(7, 2)) in LaB6 single crystal show...
Detailed ESR investigations of Mn2+ substituting for Ca2+ in Ca2Sr(C2H5COO)6, (DSP) and Ca2Pb(C2H5CO...