2-Cyanoethylzinc iodide 1 generated in over 90% yield from 3-iodopropionitrile and zinc in THF can be transmetallated to the copper and titanium derivatives 3 and 4 which react in good yields, respectively, with acyl chlorides, enones, allylic halides and benzaldehyde.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/27612/1/0000656.pd
Organozinc and copper derivatives are useful reagents in organic synthesis. Because of the high func...
Aryl- and hetero-aryl iodides react under very mild conditions (THF, 25 °C) with a Zn(Ag) couple dep...
For the preparation of zinc organometallics bearing highly sensitive functional groups such as keton...
The new copper reagent RCu(CN)ZnI 2, which may contain important functional groups like the ester, n...
The methods described herein deal with the problem of precluding protection/deprotection and functio...
Highly reactive zinc was prepared by the lithium naphthalenide reduction of zinc halides. This highl...
$unm~. The new copper eagent RCu(CN)ZnI 2, which may contain important functional groups like the es...
Functionalized aromatic iodides possessing an ester, cyano, chloride or keto group can be converted ...
Various open-chain and cyclic [beta]-cyano zinc and copper organometallics can be prepared by the re...
A catalytic amount of silver acetate efficiently promotes direct insertion of zinc metal into aryl i...
The insertion of zinc metal into primary alkyl chlorides, bromides, phosphates and sulfonates in a p...
Highly reactive copper was prepared by the lithium naphthalide reductions of various copper(I) salt/...
[alpha]-Chloroalkyl phenyl sulfides 1 readily insert zinc in THF at 25 [deg]C (0.5-2 h), affording s...
Building on recent advances in zincate chemistry, but going beyond the state-of-the-art, this proje...
A wide range of polyfunctional diaryl-and diheteroarylzinc species were prepared in toluene within 1...
Organozinc and copper derivatives are useful reagents in organic synthesis. Because of the high func...
Aryl- and hetero-aryl iodides react under very mild conditions (THF, 25 °C) with a Zn(Ag) couple dep...
For the preparation of zinc organometallics bearing highly sensitive functional groups such as keton...
The new copper reagent RCu(CN)ZnI 2, which may contain important functional groups like the ester, n...
The methods described herein deal with the problem of precluding protection/deprotection and functio...
Highly reactive zinc was prepared by the lithium naphthalenide reduction of zinc halides. This highl...
$unm~. The new copper eagent RCu(CN)ZnI 2, which may contain important functional groups like the es...
Functionalized aromatic iodides possessing an ester, cyano, chloride or keto group can be converted ...
Various open-chain and cyclic [beta]-cyano zinc and copper organometallics can be prepared by the re...
A catalytic amount of silver acetate efficiently promotes direct insertion of zinc metal into aryl i...
The insertion of zinc metal into primary alkyl chlorides, bromides, phosphates and sulfonates in a p...
Highly reactive copper was prepared by the lithium naphthalide reductions of various copper(I) salt/...
[alpha]-Chloroalkyl phenyl sulfides 1 readily insert zinc in THF at 25 [deg]C (0.5-2 h), affording s...
Building on recent advances in zincate chemistry, but going beyond the state-of-the-art, this proje...
A wide range of polyfunctional diaryl-and diheteroarylzinc species were prepared in toluene within 1...
Organozinc and copper derivatives are useful reagents in organic synthesis. Because of the high func...
Aryl- and hetero-aryl iodides react under very mild conditions (THF, 25 °C) with a Zn(Ag) couple dep...
For the preparation of zinc organometallics bearing highly sensitive functional groups such as keton...
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