The reaction of chlorotetrafluorophosphorane with trimethylamine

Kren, Robert M.
Cowley, A. H.
Smalley, M. V.

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Publication date

January 1980

DOI

10.1016/S0020-1693(00)90527-9

Publisher

Elsevier BV

ISSN

0020-1693

Abstract

The reaction of chlorotetrafluorophosphorane with trimethylamine affords a 1:1 Lewis acid-base complex of composition ClF4P[middle dot]NMe3. It has been established by 1H and 19F NMR spectroscopy that the Cl and Me3N ligands occupy mutually trans positions in a locally octahedral geometry around phosphorus.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/23385/1/0000330.pd

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The reaction of chlorotetrafluorophosphorane with trimethylamine

Abstract

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The reaction of chlorotetrafluorophosphorane with trimethylamine

Abstract

Extracted data

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