The heretofore unknown chelating fluorophosphine ligands, F2PCH2PF2 and F2PCH2CH=CH2 have been prepared and characterized. The reagent F2PCH2I has been prepared and used in the synthesis of F2PCH2PF2. NMR data are given.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/21864/1/0000268.pd
While an extensive chemistry exists for the chloro, and, to a lesser extent, the bromo and iodo phos...
A new synthesis is described for the production of a single monodentate aromatic phosphine ligand fo...
PhDChemistryUniversity of Michigan, Horace H. Rackham School of Graduate Studieshttp://deepblue.lib....
The potentially bidentate fluorophosphine ligand F2PSPF2 can be prepared in 75% yield from the react...
Reactions of the diphosphine 1,3-C6H4(CH2PH2)(2) and fluorous alkenes H2C=CHRfn (R-fn = (CF2)(n-1)CF...
This research concerns a new generation of phosphorus ligands bearing short and branched perfluoroal...
The reaction of tetrachlorodiphosphines [Cl2P(CH2)nPCl2; n = 2-4] with fluorous aromatic precursors ...
This thesis describes the use of the phosphorus analogous Mannich based condensation reaction, a pro...
http://deepblue.lib.umich.edu/bitstream/2027.42/7358/5/bad1824.0001.001.pdfhttp://deepblue.lib.umich...
Dicyclohexyl phosphine reacts with ClC=CCl(CF₂) (n = 2,3,4) and [ClC=C(CF₂)₂]₂ in DMF to give the di...
This dissertation describes the synthesis and coordination chemistry of two new phosphine ligands an...
Perfluorocyclobutene and 1,2-dichlorotetrafluorocylobutene react readily with diethylphosphine at 20...
The fluoroalkylphosphine compounds PR2Rf (R = Cy (1); Pr-i (2); R-f = CH2CH2(CF2)(5)CF3) have been p...
One particular aspect of the chemistry of the trifluoromethyl group is its high electron-withdrawing...
The fluoroalkylphosphine compounds PR2Rf (R = Cy (1); Pr-i (2); R-f = CH2CH2(CF2)(5)CF3) have been p...
While an extensive chemistry exists for the chloro, and, to a lesser extent, the bromo and iodo phos...
A new synthesis is described for the production of a single monodentate aromatic phosphine ligand fo...
PhDChemistryUniversity of Michigan, Horace H. Rackham School of Graduate Studieshttp://deepblue.lib....
The potentially bidentate fluorophosphine ligand F2PSPF2 can be prepared in 75% yield from the react...
Reactions of the diphosphine 1,3-C6H4(CH2PH2)(2) and fluorous alkenes H2C=CHRfn (R-fn = (CF2)(n-1)CF...
This research concerns a new generation of phosphorus ligands bearing short and branched perfluoroal...
The reaction of tetrachlorodiphosphines [Cl2P(CH2)nPCl2; n = 2-4] with fluorous aromatic precursors ...
This thesis describes the use of the phosphorus analogous Mannich based condensation reaction, a pro...
http://deepblue.lib.umich.edu/bitstream/2027.42/7358/5/bad1824.0001.001.pdfhttp://deepblue.lib.umich...
Dicyclohexyl phosphine reacts with ClC=CCl(CF₂) (n = 2,3,4) and [ClC=C(CF₂)₂]₂ in DMF to give the di...
This dissertation describes the synthesis and coordination chemistry of two new phosphine ligands an...
Perfluorocyclobutene and 1,2-dichlorotetrafluorocylobutene react readily with diethylphosphine at 20...
The fluoroalkylphosphine compounds PR2Rf (R = Cy (1); Pr-i (2); R-f = CH2CH2(CF2)(5)CF3) have been p...
One particular aspect of the chemistry of the trifluoromethyl group is its high electron-withdrawing...
The fluoroalkylphosphine compounds PR2Rf (R = Cy (1); Pr-i (2); R-f = CH2CH2(CF2)(5)CF3) have been p...
While an extensive chemistry exists for the chloro, and, to a lesser extent, the bromo and iodo phos...
A new synthesis is described for the production of a single monodentate aromatic phosphine ligand fo...
PhDChemistryUniversity of Michigan, Horace H. Rackham School of Graduate Studieshttp://deepblue.lib....