We report a desymmetrization of cyclohexadienones by intramolecular conjugate addition of a tethered dithiane nucleophile. Mild reaction conditions allow the formation of diversely functionalized fused bicyclic lactones. The products participate in facially selective additions from the convex surface, leading to allylic alcohol derivatives
Simple enough to be understood and complex enough to be revealing, cascade cyclizations of diepoxide...
5‐exo‐dig is a versatile Baldwin tool to predict and make useful heterocyclic compounds from nucleop...
The development of new heterocycloisomerization reactions as a tactic to access natural product scaf...
We report a desymmetrization of cyclohexadienones by intramolecular conjugate addition of a tethered...
I. Asymmetric Organocatalytic Reductive Coupling Reactions between Isatins and Aldehydes A f...
The versatility of intramolecular carbolithiation of simple unactivated alkenes to yield cyclopentyl...
A bifunctional iminophosphorane (BIMP)‐catalysed enantioselective synthesis of α,β‐unsaturated cyclo...
The title heterocyclic alcohol readily generates a sulfur-substituted allylic cation upon simple tre...
An asymmetric oxa-Michael/Michael cascade reaction of p-quinols and α,β-unsaturated aldehydes provid...
Highly enantioselective intramolecular RC reactions via desymmetrization of cyclohexadienones have b...
[EN]Hydrazones derived from cycloalkenones undergo an enantioselective transannular formal (3 + 2) c...
This thesis describes the development of diastereotopic group selective processes allowing the desym...
Herein we present the development of asymmetric deacylative allylation of ketone enolates. The react...
The authors thank the EPSRC for supporting this work and DO’H is grateful for a Royal Society Wolfso...
A pathway to benzylic [2.2]paracyclophane thiol derivatives was investigated using the benzyl Schönb...
Simple enough to be understood and complex enough to be revealing, cascade cyclizations of diepoxide...
5‐exo‐dig is a versatile Baldwin tool to predict and make useful heterocyclic compounds from nucleop...
The development of new heterocycloisomerization reactions as a tactic to access natural product scaf...
We report a desymmetrization of cyclohexadienones by intramolecular conjugate addition of a tethered...
I. Asymmetric Organocatalytic Reductive Coupling Reactions between Isatins and Aldehydes A f...
The versatility of intramolecular carbolithiation of simple unactivated alkenes to yield cyclopentyl...
A bifunctional iminophosphorane (BIMP)‐catalysed enantioselective synthesis of α,β‐unsaturated cyclo...
The title heterocyclic alcohol readily generates a sulfur-substituted allylic cation upon simple tre...
An asymmetric oxa-Michael/Michael cascade reaction of p-quinols and α,β-unsaturated aldehydes provid...
Highly enantioselective intramolecular RC reactions via desymmetrization of cyclohexadienones have b...
[EN]Hydrazones derived from cycloalkenones undergo an enantioselective transannular formal (3 + 2) c...
This thesis describes the development of diastereotopic group selective processes allowing the desym...
Herein we present the development of asymmetric deacylative allylation of ketone enolates. The react...
The authors thank the EPSRC for supporting this work and DO’H is grateful for a Royal Society Wolfso...
A pathway to benzylic [2.2]paracyclophane thiol derivatives was investigated using the benzyl Schönb...
Simple enough to be understood and complex enough to be revealing, cascade cyclizations of diepoxide...
5‐exo‐dig is a versatile Baldwin tool to predict and make useful heterocyclic compounds from nucleop...
The development of new heterocycloisomerization reactions as a tactic to access natural product scaf...