A fundamental knowledge of the interaction of carboxylic acids, such as formic acid, with magnetite surfaces is of prime importance for heterogeneous catalysis and the synthesis of novel materials. Despite this, little is known about the atomic scale adsorption mechanisms. Here we show by in-situ surface X-ray diffraction that the oxygen rich subsurface cation vacancy reconstruction of the clean magnetite (001) surface is lifted by dissociative formic acid adsorption, reestablishing a surface with bulk stoichiometry. Using density functional theory, the bulk terminated, fully formic acid covered surface is calculated to be more stable than the corresponding clean, reconstructed surface. A comparison of calculated and experimental infrared b...
Formic acid can undergo dehydration or dehydrogenation with variable selectivity over a range of met...
The surface structure of magnetite Fe3O4(111) in contact with oxygen and water is investigated using...
The interaction of water with iron oxide surfaces is relevant for several processes of practical int...
We report a novel heterogeneous adsorption mechanism of formic acid onthe magnetite (111) surface. O...
Magnetite is a versatile transition metal oxide with applications in catalysis, biomedical imaging a...
Magnetite is a material used for catalysts in some of today’s most important industrial processes,th...
The microscopic understanding of the atomic structure and interaction at carboxylic acid/oxide inter...
The adsorption of formic acid (HCOOH) on the Fe$_{3}$O$_{4}$(001) surface was studied using X-ray ph...
Although the (111) surface of Fe<sub>3</sub>O<sub>4</sub> (magnetite) has been investigated for more...
The (111) surface of magnetite, a dominant growth and fracture surface of this mineral, has been stu...
Although the (111) surface of Fe<sub>3</sub>O<sub>4</sub> (magnetite) has been investigated for more...
The interaction of water with Fe<sub>3</sub>O<sub>4</sub> (001) is studied by density functional the...
The interaction of water with Fe3O4 (001) is studied by density functional theory calculations inclu...
The adsorption of Ni, Co, Mn, Ti, and Zr at the (root 2 x root 2)R45 degrees-reconstructed Fe3O4(001...
Carboxylic-acid adsorption on anatase TiO2 is a relevant process in many technological applications....
Formic acid can undergo dehydration or dehydrogenation with variable selectivity over a range of met...
The surface structure of magnetite Fe3O4(111) in contact with oxygen and water is investigated using...
The interaction of water with iron oxide surfaces is relevant for several processes of practical int...
We report a novel heterogeneous adsorption mechanism of formic acid onthe magnetite (111) surface. O...
Magnetite is a versatile transition metal oxide with applications in catalysis, biomedical imaging a...
Magnetite is a material used for catalysts in some of today’s most important industrial processes,th...
The microscopic understanding of the atomic structure and interaction at carboxylic acid/oxide inter...
The adsorption of formic acid (HCOOH) on the Fe$_{3}$O$_{4}$(001) surface was studied using X-ray ph...
Although the (111) surface of Fe<sub>3</sub>O<sub>4</sub> (magnetite) has been investigated for more...
The (111) surface of magnetite, a dominant growth and fracture surface of this mineral, has been stu...
Although the (111) surface of Fe<sub>3</sub>O<sub>4</sub> (magnetite) has been investigated for more...
The interaction of water with Fe<sub>3</sub>O<sub>4</sub> (001) is studied by density functional the...
The interaction of water with Fe3O4 (001) is studied by density functional theory calculations inclu...
The adsorption of Ni, Co, Mn, Ti, and Zr at the (root 2 x root 2)R45 degrees-reconstructed Fe3O4(001...
Carboxylic-acid adsorption on anatase TiO2 is a relevant process in many technological applications....
Formic acid can undergo dehydration or dehydrogenation with variable selectivity over a range of met...
The surface structure of magnetite Fe3O4(111) in contact with oxygen and water is investigated using...
The interaction of water with iron oxide surfaces is relevant for several processes of practical int...