As part of a worldwide effort to develop efficient catalysts for use in organic chemistry and in the synthesis of highly valuable molecules, work performed during the course of my stay in St Andrews has focused on the design and synthesis of new group 11 metal complexes for their applications in catalysis. The aim of this work was to develop new, active and stable, easy to synthesise group 11 complexes and investigate their catalytic activity as well as to try to understand their mode of action. Two different types of complexes were explored in order to develop more active catalysts: the neutral N-Heterocyclic carbene metal complexes and the cationic derivatives. More than 20 new catalysts were developed and their reactivity studied...
N-Heterocyclic carbene ligated copper complexes act as catalysts in a variety of reactions. A brief ...
Although the chemistry of copper has a long history [1a-d], the relatively recent discovery of N-het...
N-heterosiklik karbenler; (NHCs) güçlü '-sunucu, zayıf '-alıcı, düşük toksisite, hava ve neme karşı ...
Since the discovery of persistent carbenes by the isolation of 1,3-di-l-adamantylimidazol-2-ylidene ...
The work described herein focuses on the synthesis and characterisation of copper(I) complexes beari...
Nowadays, the requirement to design highly valuable compounds is undoubtedly one of the major challe...
Les ligands de carbènes N-hétérocycliques (NHC) qui possèdent une symétrie C1 attirent beaucoup l’at...
N-Heterocyclic carbenes (NHCs) have emerged as appropriate replacements for phosphines in transitio...
The work reported in this thesis is concerned with the preparation, metal coordination and catalytic...
The work reported in this thesis is concerned with the preparation, metal coordination and catalytic...
A straightforward synthetic route has been developed permitting the formation of homoleptic and hete...
The work presented in this thesis is concerned with the synthesis, characterisation, and applicatio...
N-heterocyclic carbenes have been used as ligands for metals compounds that are function as catalyst...
N-Heterocyclic carbenes (NHCs) are powerful tools in organic chemistry, with numerous applications i...
The following body of work is a compilation of five years of research at San Diego State University ...
N-Heterocyclic carbene ligated copper complexes act as catalysts in a variety of reactions. A brief ...
Although the chemistry of copper has a long history [1a-d], the relatively recent discovery of N-het...
N-heterosiklik karbenler; (NHCs) güçlü '-sunucu, zayıf '-alıcı, düşük toksisite, hava ve neme karşı ...
Since the discovery of persistent carbenes by the isolation of 1,3-di-l-adamantylimidazol-2-ylidene ...
The work described herein focuses on the synthesis and characterisation of copper(I) complexes beari...
Nowadays, the requirement to design highly valuable compounds is undoubtedly one of the major challe...
Les ligands de carbènes N-hétérocycliques (NHC) qui possèdent une symétrie C1 attirent beaucoup l’at...
N-Heterocyclic carbenes (NHCs) have emerged as appropriate replacements for phosphines in transitio...
The work reported in this thesis is concerned with the preparation, metal coordination and catalytic...
The work reported in this thesis is concerned with the preparation, metal coordination and catalytic...
A straightforward synthetic route has been developed permitting the formation of homoleptic and hete...
The work presented in this thesis is concerned with the synthesis, characterisation, and applicatio...
N-heterocyclic carbenes have been used as ligands for metals compounds that are function as catalyst...
N-Heterocyclic carbenes (NHCs) are powerful tools in organic chemistry, with numerous applications i...
The following body of work is a compilation of five years of research at San Diego State University ...
N-Heterocyclic carbene ligated copper complexes act as catalysts in a variety of reactions. A brief ...
Although the chemistry of copper has a long history [1a-d], the relatively recent discovery of N-het...
N-heterosiklik karbenler; (NHCs) güçlü '-sunucu, zayıf '-alıcı, düşük toksisite, hava ve neme karşı ...