Fe-Ga multiple bonding? Synthesis, spectroscopic and structural characterization of a transition metal complex containing a cationic two-coordinate gallium centre.

Bunn, NR
Aldridge, S
Coombs, DL
Rossin, A
Willock, DJ
Jones, C
Ooi, LL

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Publication date

August 2004

DOI

10.1039/b405943c

Publisher

Royal Society of Chemistry (RSC)

Journal

Chemical Communications

Abstract

This communication reports the synthesis and characterization of the cationic iron complex [((eta5-C5Me5)Fe(CO)2))2Ga]+[BAr(f)4]- [Ar(f) = C6H3(CF3)2-3,5] containing a symmetrically bridging two-coordinate gallium atom and a delocalised Fe-Ga-Fe pi system incorporating partial Fe-Ga multiple bond character

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Fe-Ga multiple bonding? Synthesis, spectroscopic and structural characterization of a transition metal complex containing a cationic two-coordinate gallium centre.

Abstract

Extracted data

Fe-Ga multiple bonding? Synthesis, spectroscopic and structural characterization of a transition metal complex containing a cationic two-coordinate gallium centre.

Abstract

Extracted data

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