Solid-state reaction of FeSO4·7H2O and 1,10-phenanthroline in a 1:1 molar ratio was investigated by time-resolved in-situ energy dispersive X-ray diffraction (EDXRD), DSC, TG/DTA, Mössbauer and IR spectroscopy. The reaction of these solids takes place rapidly at around 70°C and initially produces an intermediate crystalline phase, Fe(phen)3SO4·5H2O before cleanly converting to Fe(phen)(H2O)3SO4. This is in contrast to the product of the reaction of FeSO4·7H2O with 1,10-phenanthroline in aqueous solution which produces [Fe(phen)32+][SO42-]. All the spectral data suggest that the final product is a neutral Fe(II) complex. The coordination sphere around the Fe(II) ions is thought to be octahedral consisting of a unidentate sulfate ligand, a bi...
Reaction of (μ-S2)Fe2(CO)6 (1) with 1 equiv of thiolate RS- (R = Ph, PhCH2, i-Pr) results in formati...
Djenkolate complex of iron, [Fe(C(7)H(12)N(2)O(4)S(2))]. H(2)O, has been synthesized by the reaction...
The cluster complex (C5H5)(4)Fe4S4 formally contains Fe(III) and sulfide as constituents. In agreeme...
Solid-state reaction of FeSO4·7H2O and 1,10-phenanthroline in a 1:1 molar ratio was investigated by ...
Monoclinic FeSO4·7H2O is the stable solid phase between -1.82° and 56.6° C in contact with a saturat...
We report in this paper a new crystal-chemical study of synthetic basic ferric sulfate FeOHSO4. The ...
A new sustainable process was developed to recycle FeSO4 center dot 7H(2)O produced from the sulfate...
930-934An iron-sulphur cluster complex, Fe4(HSCH2CH2SH)2(CO)12 (I) has been synthesized by thermal r...
AbstractWe report in this paper a new crystal-chemical study of synthetic basic ferric sulfate FeOHS...
International audienceThe reaction of Fe-2(CO)(9) with phenyldithiobenzoate PhCS2Ph 1 afforded four ...
Iron oxides are transition metal oxides of paramount importance for their technological applications...
We have been studying chemical processes that use discrete molecular reagents to form extended solid...
International audienceThe addition of a solution of tetrathiosquarate using K2C4S4·H2O to an aqueous...
Les complexes FeSO4.7 H2O, FeSO4.4 H2O, FeSO4. H2O, FeSO4 ont été irradiés aux rayonnements γ du 60C...
International audienceThe thermal decomposition of FeSO4•6H2O was studied by mass spectroscopy coupl...
Reaction of (μ-S2)Fe2(CO)6 (1) with 1 equiv of thiolate RS- (R = Ph, PhCH2, i-Pr) results in formati...
Djenkolate complex of iron, [Fe(C(7)H(12)N(2)O(4)S(2))]. H(2)O, has been synthesized by the reaction...
The cluster complex (C5H5)(4)Fe4S4 formally contains Fe(III) and sulfide as constituents. In agreeme...
Solid-state reaction of FeSO4·7H2O and 1,10-phenanthroline in a 1:1 molar ratio was investigated by ...
Monoclinic FeSO4·7H2O is the stable solid phase between -1.82° and 56.6° C in contact with a saturat...
We report in this paper a new crystal-chemical study of synthetic basic ferric sulfate FeOHSO4. The ...
A new sustainable process was developed to recycle FeSO4 center dot 7H(2)O produced from the sulfate...
930-934An iron-sulphur cluster complex, Fe4(HSCH2CH2SH)2(CO)12 (I) has been synthesized by thermal r...
AbstractWe report in this paper a new crystal-chemical study of synthetic basic ferric sulfate FeOHS...
International audienceThe reaction of Fe-2(CO)(9) with phenyldithiobenzoate PhCS2Ph 1 afforded four ...
Iron oxides are transition metal oxides of paramount importance for their technological applications...
We have been studying chemical processes that use discrete molecular reagents to form extended solid...
International audienceThe addition of a solution of tetrathiosquarate using K2C4S4·H2O to an aqueous...
Les complexes FeSO4.7 H2O, FeSO4.4 H2O, FeSO4. H2O, FeSO4 ont été irradiés aux rayonnements γ du 60C...
International audienceThe thermal decomposition of FeSO4•6H2O was studied by mass spectroscopy coupl...
Reaction of (μ-S2)Fe2(CO)6 (1) with 1 equiv of thiolate RS- (R = Ph, PhCH2, i-Pr) results in formati...
Djenkolate complex of iron, [Fe(C(7)H(12)N(2)O(4)S(2))]. H(2)O, has been synthesized by the reaction...
The cluster complex (C5H5)(4)Fe4S4 formally contains Fe(III) and sulfide as constituents. In agreeme...