BIFUNCTIONAL CHIRAL AUXILIARIES-3 - SYNTHESIS OF HOMOCHIRAL 1,3-DIOLS VIA ASYMMETRIC ALDOL REACTIONS OF DIALKYLBORON ENOLATES OF 1,3-DIPROPIONYL-TRANS-4,5-DIPHENYL-IMIDAZOLIDIN-2-ONE AND ALDEHYDES

DAVIES, S
MORTLOCK, A

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Publication date

January 1991

DOI

10.1016/S0957-4166(00)86148-0

Publisher

Elsevier BV

Journal

Tetrahedron Asymmetry

Abstract

Dibutylboron enolates derived from both racemic and homochiral 1,3-dipropionyl-trans-4,5-diphenylimidazolidin-2-one 3 react with aldehydes in highly diastereoselective dialdol reactions to give, after reductive cleavage of the acyl sidechain, substituted 1,3-diols. © 1991

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BIFUNCTIONAL CHIRAL AUXILIARIES-3 - SYNTHESIS OF HOMOCHIRAL 1,3-DIOLS VIA ASYMMETRIC ALDOL REACTIONS OF DIALKYLBORON ENOLATES OF 1,3-DIPROPIONYL-TRANS-4,5-DIPHENYL-IMIDAZOLIDIN-2-ONE AND ALDEHYDES

Abstract

Extracted data

BIFUNCTIONAL CHIRAL AUXILIARIES-3 - SYNTHESIS OF HOMOCHIRAL 1,3-DIOLS VIA ASYMMETRIC ALDOL REACTIONS OF DIALKYLBORON ENOLATES OF 1,3-DIPROPIONYL-TRANS-4,5-DIPHENYL-IMIDAZOLIDIN-2-ONE AND ALDEHYDES

Abstract

Extracted data

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