The expansion of shock waves has been studied in mediums with different opacities and heat capacities, varied in systematic ways by mixing xenon with nitrogen keeping the mass density constant. An initial shock is generated through the brief (5 ns) deposition of laser energy (5 J) on the tip of a pin surrounded by the xenon-nitrogen mixture. The initial shock is spherical, radiative, with a high Mach number, and it sends a supersonic radiatively driven heat wave far ahead of itself. The heat wave rapidly slows to a transonic regime and when its Mach number drops to ∼2 with respect to the downstream plasma, the heat wave becomes of the ablative type, driving a second shock ahead of itself to satisfy mass and momentum conservation in the heat...