A rigorous analytical solution for Reverse Pulse Voltammetry (RPV) at spherical electrodes of all sizes is presented, including the case where the diffusion coefficients of the electroactive species are different. From this solution, the value of RPV for the determination of both diffusion coefficients and the formal potential of the redox couple is demonstrated. The experimental application of the theoretical results is carried out both in ionic liquids and in aqueous solution with mercury microelectrodes of ca. 50 and 10 μm diameters. The former solvent system is of particular interest due to the great importance of these new liquids in which notably unequal diffusion coefficients are commonly found. © 2009 Elsevier B.V. All rights reserv...
The electrochemical properties of the room temperature ionic liquids 1-butyl-3-methylimidazolium tet...
Ionic liquids provide high viscosity solvent environments with interesting voltammetric characterist...
We present a general and explicit analytical solution for double potential step chronoamperometry wi...
Rigorous and approximate analytical expressions are deduced for Differential Pulse Voltammetry at sp...
Reverse Pulse Voltammetry (RPV) is a powerful double pulse technique for kinetic studies. The theory...
Reverse Pulse Voltammetry (RPV) is a powerful double pulse technique for kinetic studies. The theory...
The study of the EC mechanism by reverse pulse voltammetry (RPV) is assessed in this paper. RPV is a...
This thesis is concerned with investigating the suitability of room temperature ionic liquids as sol...
Scanning electrochemical microscopy offers interesting possibilities for investigating both transpor...
Scanning electrochemical microscopy offers interesting possibilities for investigating both transpor...
Scanning electrochemical microscopy offers interesting possibilities for investigating both transpor...
Ionic liquids provide high viscosity solvent environments with interesting voltammetric characterist...
The voltammetry of N,N-dimethyl-p-phenylenediamine, DMPD, in the room temperature ionic liquid (RTIL...
Numerical simulation is used to characterise double potential step chronoamperometry at a microband ...
The electrochemical properties of the room temperature ionic liquids 1-butyl-3-methylimidazolium tet...
The electrochemical properties of the room temperature ionic liquids 1-butyl-3-methylimidazolium tet...
Ionic liquids provide high viscosity solvent environments with interesting voltammetric characterist...
We present a general and explicit analytical solution for double potential step chronoamperometry wi...
Rigorous and approximate analytical expressions are deduced for Differential Pulse Voltammetry at sp...
Reverse Pulse Voltammetry (RPV) is a powerful double pulse technique for kinetic studies. The theory...
Reverse Pulse Voltammetry (RPV) is a powerful double pulse technique for kinetic studies. The theory...
The study of the EC mechanism by reverse pulse voltammetry (RPV) is assessed in this paper. RPV is a...
This thesis is concerned with investigating the suitability of room temperature ionic liquids as sol...
Scanning electrochemical microscopy offers interesting possibilities for investigating both transpor...
Scanning electrochemical microscopy offers interesting possibilities for investigating both transpor...
Scanning electrochemical microscopy offers interesting possibilities for investigating both transpor...
Ionic liquids provide high viscosity solvent environments with interesting voltammetric characterist...
The voltammetry of N,N-dimethyl-p-phenylenediamine, DMPD, in the room temperature ionic liquid (RTIL...
Numerical simulation is used to characterise double potential step chronoamperometry at a microband ...
The electrochemical properties of the room temperature ionic liquids 1-butyl-3-methylimidazolium tet...
The electrochemical properties of the room temperature ionic liquids 1-butyl-3-methylimidazolium tet...
Ionic liquids provide high viscosity solvent environments with interesting voltammetric characterist...
We present a general and explicit analytical solution for double potential step chronoamperometry wi...