Unambiguous enantiospecific syntheses of 1,5-dideoxy-1,5-imino-D-mannitol (LU1, 1-deoxy-mannojirimycin) are reported (i) from D-mannose via hydrogenation of a 5-azido-5-deoxy mannose, and (ii) from D-glucose, in which the key step involves nucleophilic substitution of a trifluoromethanesulphonyl group from C-2 of D-glucose. © 1984
2,3,6-Tri-O-benzyl-D-myo-inositol, which is a key intermediate of D-inositol 1,4,5-triphosphate, was...
D-Mannitol was simultaneously tritylated and acetylated to give 1,6-di-0-trityl-D-mannitol tetraacet...
An efficient route to orthogonally protected L-glucose, L-mannose, and L-galactose is described. Usi...
Methyl 2-azido-3-O-benzyl-2-deoxy-α-D-mannofuranoside (4), readily available from D-glucose, is a co...
The isoxazoline obtained by 1,3-dipolar cycloaddition of 2,2-diethoxyacetonitrile N-oxide to furan w...
(3R,4R)-O-isopropylidene-1,6-Hexanediol 1 has been synthesized from a readily available D-mannitol d...
The synthesis of methyl 2-azido-3-O-benzyl-2-deoxy-α-D-mannofuranoside (1) from D-glucose is reporte...
Total synthesis of (−)-lentiginosine was achieved from D-mannitol using highly stereoselective react...
Enantiomerically pure 1,5-dideoxy-1,5-imino-D-glycero-D-allo-heptitol (10) has been synthesized in c...
Short syntheses of D-deoxymannojirimycin and of D-mannonolactam from L-gulonolactone are reported; i...
An eight step synthesis of deoxymannojirimycin from L-gulonolactone in 25% overall yield is reported...
A stereodivergent synthesis of 1,4-dideoxy-1,4-imino-d-mannitol I and d-allitol III from an (S)-glyc...
2-C-Methylene-N-glycosyl amides have been obtained from 2-(hydroxymethyl)glycals through a facile az...
The value of methyl 3-O-benzyl-2,6-dideoxy-2,6-imino-α-D-mannofuranoside as a divergent intermediate...
Azasugars are structural analogues of carbohydrates whereby the oxygen in the heterocyclic ring is s...
2,3,6-Tri-O-benzyl-D-myo-inositol, which is a key intermediate of D-inositol 1,4,5-triphosphate, was...
D-Mannitol was simultaneously tritylated and acetylated to give 1,6-di-0-trityl-D-mannitol tetraacet...
An efficient route to orthogonally protected L-glucose, L-mannose, and L-galactose is described. Usi...
Methyl 2-azido-3-O-benzyl-2-deoxy-α-D-mannofuranoside (4), readily available from D-glucose, is a co...
The isoxazoline obtained by 1,3-dipolar cycloaddition of 2,2-diethoxyacetonitrile N-oxide to furan w...
(3R,4R)-O-isopropylidene-1,6-Hexanediol 1 has been synthesized from a readily available D-mannitol d...
The synthesis of methyl 2-azido-3-O-benzyl-2-deoxy-α-D-mannofuranoside (1) from D-glucose is reporte...
Total synthesis of (−)-lentiginosine was achieved from D-mannitol using highly stereoselective react...
Enantiomerically pure 1,5-dideoxy-1,5-imino-D-glycero-D-allo-heptitol (10) has been synthesized in c...
Short syntheses of D-deoxymannojirimycin and of D-mannonolactam from L-gulonolactone are reported; i...
An eight step synthesis of deoxymannojirimycin from L-gulonolactone in 25% overall yield is reported...
A stereodivergent synthesis of 1,4-dideoxy-1,4-imino-d-mannitol I and d-allitol III from an (S)-glyc...
2-C-Methylene-N-glycosyl amides have been obtained from 2-(hydroxymethyl)glycals through a facile az...
The value of methyl 3-O-benzyl-2,6-dideoxy-2,6-imino-α-D-mannofuranoside as a divergent intermediate...
Azasugars are structural analogues of carbohydrates whereby the oxygen in the heterocyclic ring is s...
2,3,6-Tri-O-benzyl-D-myo-inositol, which is a key intermediate of D-inositol 1,4,5-triphosphate, was...
D-Mannitol was simultaneously tritylated and acetylated to give 1,6-di-0-trityl-D-mannitol tetraacet...
An efficient route to orthogonally protected L-glucose, L-mannose, and L-galactose is described. Usi...