Syntheses of trans-SCH-A and cis-SCH-A via a stereodivergent cyclopropanation protocol.
- Csatayová, K
- Davies, SG
- Lee, JA
- Ling, KB
- Roberts, PM
- Russell, AJ
- Thomson, JE
Publication date
July 2010
DOI Publisher
American Chemical Society (ACS) Journal
Organic LettersAbstract
A highly diastereoselective cyclopropanation protocol has been employed in the syntheses of trans-SCH-A and cis-SCH-A. This strategy encompasses a stereodivergent procedure for the preparation of syn- and anti-cyclopropane diastereoisomers in high dr from a common allylic carbamate precursor
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