CARBOCYCLIC RING EXPANSION REACTIONS VIA RADICAL CHAIN PROCESSES

BALDWIN, J
ADLINGTON, R
Robertson, J

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Publication date

January 1989

DOI

10.1016/0040-4020(89)80003-1

Publisher

Elsevier BV

Journal

Tetrahedron

Abstract

A free radical mediated ring expansion of cis- and trans- α-alkylated-β-stannylcyclohexanones to provide efficient routes tocis- andtrans-cyclononenones and cyclodecenones is described. The cis-/trans- relationship in the precursor was found to have significant bearing on the alkene geometry of the ring expanded product. © 1989

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CARBOCYCLIC RING EXPANSION REACTIONS VIA RADICAL CHAIN PROCESSES

Abstract

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CARBOCYCLIC RING EXPANSION REACTIONS VIA RADICAL CHAIN PROCESSES

Abstract

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