Stretchable Self-Healable Semiconducting Polymer Film for Active-Matrix Strain-Sensing Array

Skin-like sensory devidces shoud be stretchable and self-healable to meet the demands for future electronic skin applications. Despite recent notable advances in skin-inspired electronic materials, it remains challenging to confer these desired functionalities to an active semiconductor. Here, we report a strain-sensitive, stretchable, and autonomously self-healable semiconducting film achieved through blending of a polymer semiconductor and a self-healable elastomer, both of which are dynamically cross-linked by metal coordination. We observed that by controlling the percolation threshold of the polymer semiconductor, the blend film became strain sensitive, with a gauge factor of 5.75 x 105 at 100% strain in a stretchable transistor. The blend film is also highly stretchable (fracture strain, \u3e1300%) and autonomously self-healable at room temperature. We proceed to demonstrate a fully integrated 5 x 5 stretchable active-matrix transistor sensor array capable of detecting strain distribution through surface deformation