Luminescence of Hg(3P1) atoms trapped in mixed Ar/Xe matrices containing a small amount of Xe is reported. Broad emission bands, strongly red-shifted from absorption are recorded which are assigned to strong complexes formed between the excited mercury Hg* and xenon atoms. Molecular dynamics calculations are performed on simulated Xe/Ar samples doped with Hg to follow the behavior of Hg* in the mixed rare gas matrices leading to exciplex formation. The role of Xe atoms in the first solvation shell (SS1) around Hg was investigated in detail, revealing the formation of two kinds of triatomic exciplexes; namely, Xe–Hg*–Xe and Ar–Hg*–Xe. The first species exists only when two xenon atoms are present in SS1 with specific geometries allowing the ...
Van der Waals clusters involving mercury have been studied in a supersonic expansion beam crossed wi...
Photochemical processes in Xe and NF3 doped rare gas clusters RgN (Rg=Ar, Kr, Xe) are investigated w...
The emission and direct excitation spectra of XeH (D) and Xe$_2$H(D) were observed after photolysis ...
Luminescence of Hg(3P1) atoms trapped in mixed Ar/Xe matrices containing a small amount of Xe is rep...
Pair-potentials calculations of the 3P1↔1S0 absorption and emission energies of atomic mercury isola...
Multicomponent emission bands are recorded for the 3P1→1S0 transition of atomic mercury isolated at ...
Author Institution: B. Verkin Institute for Low Temperature Physics and Engineering, Ukrainian Acade...
The work presented in this thesis is primarily experimental but also contains an important theoreti...
Author Institution: Department of Chemistry, Emory University, Atlanta, GA 30322Electronic spectra f...
The excitation and emission spectra of Ar2H(D) in Ar, Kr2H(D) in Kr and Xe2H(D) in Ar, Kr, Xe were o...
The absorption and emission spectra of the 3P1-1S0 transition of a Hg atom embedded in solid Ar were...
References: Neutral rare-gas containing charge-transfer molecules in solid matrices. I. HXeCl, HXeBr...
Irradiation of atomic europium isolated in the solid rare gases, with low intensity laser excitation...
Using a clean preparation technique of doping alkali atoms in argon matrices, VUV emissions of the c...
The emission spectra of ArXeH, ArKrD in an argon matrix and KrXeD in a krypton matrix were observed ...
Van der Waals clusters involving mercury have been studied in a supersonic expansion beam crossed wi...
Photochemical processes in Xe and NF3 doped rare gas clusters RgN (Rg=Ar, Kr, Xe) are investigated w...
The emission and direct excitation spectra of XeH (D) and Xe$_2$H(D) were observed after photolysis ...
Luminescence of Hg(3P1) atoms trapped in mixed Ar/Xe matrices containing a small amount of Xe is rep...
Pair-potentials calculations of the 3P1↔1S0 absorption and emission energies of atomic mercury isola...
Multicomponent emission bands are recorded for the 3P1→1S0 transition of atomic mercury isolated at ...
Author Institution: B. Verkin Institute for Low Temperature Physics and Engineering, Ukrainian Acade...
The work presented in this thesis is primarily experimental but also contains an important theoreti...
Author Institution: Department of Chemistry, Emory University, Atlanta, GA 30322Electronic spectra f...
The excitation and emission spectra of Ar2H(D) in Ar, Kr2H(D) in Kr and Xe2H(D) in Ar, Kr, Xe were o...
The absorption and emission spectra of the 3P1-1S0 transition of a Hg atom embedded in solid Ar were...
References: Neutral rare-gas containing charge-transfer molecules in solid matrices. I. HXeCl, HXeBr...
Irradiation of atomic europium isolated in the solid rare gases, with low intensity laser excitation...
Using a clean preparation technique of doping alkali atoms in argon matrices, VUV emissions of the c...
The emission spectra of ArXeH, ArKrD in an argon matrix and KrXeD in a krypton matrix were observed ...
Van der Waals clusters involving mercury have been studied in a supersonic expansion beam crossed wi...
Photochemical processes in Xe and NF3 doped rare gas clusters RgN (Rg=Ar, Kr, Xe) are investigated w...
The emission and direct excitation spectra of XeH (D) and Xe$_2$H(D) were observed after photolysis ...