The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH2R) complexes with water

Lee, Jia Ying
Fan, Wai Yip
Mak, Garvin Kar Hang
Leong, Weng Kee

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Publication date

January 2012

DOI

10.1016/j.jorganchem.2012.11.030

Publisher

Elsevier BV

Journal

Journal of Organometallic Chemistry

Abstract

The iridium complexes Cp*Ir(CO)(Cl)(CH2R), which do not contain any β-hydrogen atoms, react with water to form aldehydes. This reaction was found to be photochemically activated, and a possible pathway involving radical intermediates has been proposed and studied experimentally and computationally.MOE (Ministry of Education)Accepted versio

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The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH2R) complexes with water

Abstract

Extracted data

The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH2R) complexes with water

Abstract

Extracted data

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