Add to ORKGThe possibility of catalyzing asymmetric reaction without the use of metal complex, but with purely organic compounds has gained much attention recently. The term “organocatalysts” was thus coined out to describe this new field of the organic chemistry. An example of the organocatalysts is (S)-proline, a widely available amino acid, which was found to be an extremely effective catalyst for the aldol reaction, affording excellent enantioselectivities. The drive to explore alternative potential organocatalysts other than (S)-proline provided the motivation to explore efficiency of 1’,2’,3’,4’-tetrahydro-1,1’-biisoquinoline (BIQ) and its derivatives in the asymmetric aldol reaction. In the first half of the project, BIQ, which functions as ...
In asymmetric synthesis of organic compounds more effective solutions are being looked for which wil...
Density functional theory has been employed in investigating the efficiency of a series of bicyclic ...
L-Prolinamides 2, prepared from L-proline and simple aliphatic and aromatic amines, have been found ...
The possibility of catalyzing asymmetric reaction without the use of metal complex, but with purely ...
Most enzymatic transformations have a synthetic counterpart. Often though, the mechanisms by which n...
A series of novel proline-based organocatalysts with amide and thiourea-amine units (7a-f) were dev...
A new family of bile acid derived organocatalysts was obtained by linking L- or D-proline to amino d...
Proline in organic synthesis is used as a small molecular organocatalyst. In a catalytic act proline...
The organocatalytic iminium activation strategy acting cooperatively with a Lewis acidic group has b...
L-Prolinamides 2, prepared from L-proline and simple aliphatic and aromatic amines, have been found ...
In this article the utility of water-compatible amino-acid-based catalysts was explored in the devel...
At the beginning of the 21st century, organocatalysis has emerged as a new powerful methodology for ...
This thesis details the syntheses of catalysts and their applications in asymmetric reactions. Initi...
Organocatalysis, catalysis with low-molecular weight catalysts in which a metal is not part of the c...
In this article the utility of water-compatible amino-acid-based catalysts was explored in the deve...
In asymmetric synthesis of organic compounds more effective solutions are being looked for which wil...
Density functional theory has been employed in investigating the efficiency of a series of bicyclic ...
L-Prolinamides 2, prepared from L-proline and simple aliphatic and aromatic amines, have been found ...
The possibility of catalyzing asymmetric reaction without the use of metal complex, but with purely ...
Most enzymatic transformations have a synthetic counterpart. Often though, the mechanisms by which n...
A series of novel proline-based organocatalysts with amide and thiourea-amine units (7a-f) were dev...
A new family of bile acid derived organocatalysts was obtained by linking L- or D-proline to amino d...
Proline in organic synthesis is used as a small molecular organocatalyst. In a catalytic act proline...
The organocatalytic iminium activation strategy acting cooperatively with a Lewis acidic group has b...
L-Prolinamides 2, prepared from L-proline and simple aliphatic and aromatic amines, have been found ...
In this article the utility of water-compatible amino-acid-based catalysts was explored in the devel...
At the beginning of the 21st century, organocatalysis has emerged as a new powerful methodology for ...
This thesis details the syntheses of catalysts and their applications in asymmetric reactions. Initi...
Organocatalysis, catalysis with low-molecular weight catalysts in which a metal is not part of the c...
In this article the utility of water-compatible amino-acid-based catalysts was explored in the deve...
In asymmetric synthesis of organic compounds more effective solutions are being looked for which wil...
Density functional theory has been employed in investigating the efficiency of a series of bicyclic ...
L-Prolinamides 2, prepared from L-proline and simple aliphatic and aromatic amines, have been found ...