The Grignard compounds MeMgBr and EtMgBr in n-Bu2O were studied at room temperature and — 85°C by extended X-ray absorption fine structure (EXAFS) spectroscopy above the magnesium and bromine K edges. The magnesium EXAFS studies were performed in the fluorescence mode with an UHV compatible cell for liquid samples. At both temperatures, dimers of the Grignard compounds are observed. By a combined analysis of the magnesium and bromine EXAFS spectra, the structure of the dimers of the Grignard compounds is deduced. Copyright © 1996 Elsevier Science Lt
Extended X-ray Absorption Fine Structure (EXAFS) measurements are reported for crystalline solids α ...
Crotyl bromide and α-methylallyl bromide each react with magnesium in ether to yield the same buteny...
X‐ray absorption spectroscopy is widely employed in the structural analysis of disordered systems. I...
The Grignard compounds MeMgBr and EtMgBr in n-Bu2O were studied at room temperature and — 85°C by ex...
The results of an EXAFS study of the Grignard compounds methyl, ethyl and phenyl magnesium bromide i...
Grignard Compounds RMgX (R=organic group ; X=Cl, Br, I) are common tools in inorganic and organic sy...
Much has been said but little settled about the precise nature of the Grignard reagent. The X-ray st...
The structure of the dimeric ethylmagnesium bromide/diisopropyl ether complex [C2H5MgBr - O(i-C3H7)2...
Author Institution: Department of Chemistry, University of VirginiaMagnesium atoms were generated by...
X‐ray absorption spectroscopy is widely employed in the structural analysis of disordered systems. I...
En vue d'étudier la transition métal-non métal que présentent les systèmes désordonnés tels que les ...
1. Y. Imuzu, and K.J. Klabunde, Inorgan, Chem, 23, 3602 (1984) 2. B.S. Ault. JACS 102, 3480 (1980) 3...
EXAFS and XANES measurements were systematically performed on various systems containing brominated ...
The composition of Grignard reagents has been studied extensively by nuclear magnetic resonance spec...
The EXAFS (extended X-ray absorption fine structure) method was applied to the state analysis of the...
Extended X-ray Absorption Fine Structure (EXAFS) measurements are reported for crystalline solids α ...
Crotyl bromide and α-methylallyl bromide each react with magnesium in ether to yield the same buteny...
X‐ray absorption spectroscopy is widely employed in the structural analysis of disordered systems. I...
The Grignard compounds MeMgBr and EtMgBr in n-Bu2O were studied at room temperature and — 85°C by ex...
The results of an EXAFS study of the Grignard compounds methyl, ethyl and phenyl magnesium bromide i...
Grignard Compounds RMgX (R=organic group ; X=Cl, Br, I) are common tools in inorganic and organic sy...
Much has been said but little settled about the precise nature of the Grignard reagent. The X-ray st...
The structure of the dimeric ethylmagnesium bromide/diisopropyl ether complex [C2H5MgBr - O(i-C3H7)2...
Author Institution: Department of Chemistry, University of VirginiaMagnesium atoms were generated by...
X‐ray absorption spectroscopy is widely employed in the structural analysis of disordered systems. I...
En vue d'étudier la transition métal-non métal que présentent les systèmes désordonnés tels que les ...
1. Y. Imuzu, and K.J. Klabunde, Inorgan, Chem, 23, 3602 (1984) 2. B.S. Ault. JACS 102, 3480 (1980) 3...
EXAFS and XANES measurements were systematically performed on various systems containing brominated ...
The composition of Grignard reagents has been studied extensively by nuclear magnetic resonance spec...
The EXAFS (extended X-ray absorption fine structure) method was applied to the state analysis of the...
Extended X-ray Absorption Fine Structure (EXAFS) measurements are reported for crystalline solids α ...
Crotyl bromide and α-methylallyl bromide each react with magnesium in ether to yield the same buteny...
X‐ray absorption spectroscopy is widely employed in the structural analysis of disordered systems. I...