Copper-phthalocyanine based metal-organic interfaces: The effect of fluorination, the substrate, and its symmetry
- De Oteyza, D. G.
- El-sayed, A.
- Garcia-lastra, J. M.
- Goiri, E.
- Krauss, T. N.
- Turak, A.
- Barrena, E.
- Dosch, H.
- Zegenhagen, J.
- Rubio, A.
- Wakayama, Y.
- Ortega, J. E.
DOIAbstract
Metal-organic interfaces based on copper-phthalocyanine monolayers are studied in dependence of the metal substrate (Au versus Cu), of its symmetry [hexagonal (111) surfaces versus fourfold (100) surfaces], as well as of the donor or acceptor semiconducting character associated with the nonfluorinated or perfluorinated molecules, respectively. Comparison of the properties of these systematically varied metal-organic interfaces provides new insight into the effect of each of the previously mentioned parameters on the molecule-substrate interactions
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