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lewis baseEukaryote
silyleneChemical substance
1013-1017Ab initio calculations show that silylenes can show lewis acidic behaviour. The complexation between silylenes and lewis bases proceeds without energy barrier. The resultant silylene-lewis base complexes show nucleophilicity. The larger the stabilization between silylene and lewis base, the larger is the nucleophilicity of the resultant complex. Silylenes can show nucleophilicity only after their electrophilicity gets satisfied
As the importance and abundance of silicon in our environment is large, it has been thought that sil...
The reactivity of a series of silylium ion/phosphane Lewis pairs was studied. Triarylsilylium borate...
Quantum chemical calculations at the semi-empirical, Hartree-Fock and correlated ab initio levels ha...
In this paper we have reported for the first time some designed silylene superbases using DFT calcul...
The Lewis acidity of several aryl-substituted tetrylium ions was classified experimentally by applyi...
The Lewis acidity of several aryl-substituted tetrylium ions was classified experimentally by applyi...
The Lewis acidity of several aryl-substituted tetrylium ions was classified experimentally by applyi...
Two dicoordinate silicon compounds have been prepared, the unsaturated silylene 4 and the saturated ...
The Lewis acid–base complexation reactions of dimethyl-, diphenyl-, and dimesitylsilylene (SiMe<sub>...
[[abstract]]This chapter presents a study on inorganic silylenes focusing on the chemistry of silyle...
International audienceA novel architecture of phosphine-stabilized silylium ions is described. The p...
Cette thèse a pour but d’étudier et d’approfondir les connaissances actuelles dans le domaine de la ...
Cette thèse a pour but d’étudier et d’approfondir les connaissances actuelles dans le domaine de la ...
Cette thèse a pour but d’étudier et d’approfondir les connaissances actuelles dans le domaine de la ...
The isomerization of silylallene to seven of its isomers has been studied using ab initio molecular ...
As the importance and abundance of silicon in our environment is large, it has been thought that sil...
The reactivity of a series of silylium ion/phosphane Lewis pairs was studied. Triarylsilylium borate...
Quantum chemical calculations at the semi-empirical, Hartree-Fock and correlated ab initio levels ha...
In this paper we have reported for the first time some designed silylene superbases using DFT calcul...
The Lewis acidity of several aryl-substituted tetrylium ions was classified experimentally by applyi...
The Lewis acidity of several aryl-substituted tetrylium ions was classified experimentally by applyi...
The Lewis acidity of several aryl-substituted tetrylium ions was classified experimentally by applyi...
Two dicoordinate silicon compounds have been prepared, the unsaturated silylene 4 and the saturated ...
The Lewis acid–base complexation reactions of dimethyl-, diphenyl-, and dimesitylsilylene (SiMe<sub>...
[[abstract]]This chapter presents a study on inorganic silylenes focusing on the chemistry of silyle...
International audienceA novel architecture of phosphine-stabilized silylium ions is described. The p...
Cette thèse a pour but d’étudier et d’approfondir les connaissances actuelles dans le domaine de la ...
Cette thèse a pour but d’étudier et d’approfondir les connaissances actuelles dans le domaine de la ...
Cette thèse a pour but d’étudier et d’approfondir les connaissances actuelles dans le domaine de la ...
The isomerization of silylallene to seven of its isomers has been studied using ab initio molecular ...
As the importance and abundance of silicon in our environment is large, it has been thought that sil...
The reactivity of a series of silylium ion/phosphane Lewis pairs was studied. Triarylsilylium borate...
Quantum chemical calculations at the semi-empirical, Hartree-Fock and correlated ab initio levels ha...
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