787-799A comparison of vapour pressure isotope effect (VPIE) in single ionic solutions, i.e., hydrogen isotope effects in the dehydration of alkali metal ionic forms of resins (Li+, Na+, K+ and Cs+- forms) and corresponding aqueous alkali metal chloride solutions at various concentrations and temperatures has been made. Theory of VPIE for cationic solutions having 3 water sub-systems and anionic solutions having 2 water sub-systems has been developed. Single ion solutions (Li+ at 303K, Na + at 318K, K+ at 333K and Cs + at 353K) show all the features arising from the hydration shell models and predicted by the theory of VPIE in their a (separation factor) versus m (molality) plots. The absence of these features in the a versus m plots in l...
Abstract — The principle of corresponding states is valid in reasonable approximation for ionic flui...
A simple method is proposed for estimating the vapour pressures of aqueous single electrolyte soluti...
Alkali metal cations play vital roles in chemical and biochemical systems. Lithium is widely used in...
313-321Hydrogen isotope effects in dehydration of alkali metal ionic (Li+, K+ and Cs+) forms of Dowe...
409-417A molecular level interpretation of ion exchange selectivity has to be based on various types...
Abstract We describe a simple electrostatic model of hydrated ions [M(H2O)n]+ (n = 3–18, M = Li, M...
Measurements of the vapor pressure of the solvent in wide ranges of concentration and temperature pr...
Systematic researches in recent years have revived the earlier ideas of ionic association/dissociati...
Author Institution: Department of Chemistry, University of Illinois, Urbana, IL 61801The role of tem...
The hydration of the alkali metal ions in aqueous solution has been studied by large angle X-ray sca...
This work deals with the effect of increasing pressure at 298.15 K on the structure and hydration sh...
This work is a new development of an extensive research program that is investigating for the first ...
Neutron diffraction experiments with hydrogen isotope substitution on aqueous solutions of HCl and H...
Understanding the performance of individual ions in salt solutions and the consequence of ionic hydr...
Pressure perturbation calorimetry (PPC) was used to study the relationship between water and sodium ...
Abstract — The principle of corresponding states is valid in reasonable approximation for ionic flui...
A simple method is proposed for estimating the vapour pressures of aqueous single electrolyte soluti...
Alkali metal cations play vital roles in chemical and biochemical systems. Lithium is widely used in...
313-321Hydrogen isotope effects in dehydration of alkali metal ionic (Li+, K+ and Cs+) forms of Dowe...
409-417A molecular level interpretation of ion exchange selectivity has to be based on various types...
Abstract We describe a simple electrostatic model of hydrated ions [M(H2O)n]+ (n = 3–18, M = Li, M...
Measurements of the vapor pressure of the solvent in wide ranges of concentration and temperature pr...
Systematic researches in recent years have revived the earlier ideas of ionic association/dissociati...
Author Institution: Department of Chemistry, University of Illinois, Urbana, IL 61801The role of tem...
The hydration of the alkali metal ions in aqueous solution has been studied by large angle X-ray sca...
This work deals with the effect of increasing pressure at 298.15 K on the structure and hydration sh...
This work is a new development of an extensive research program that is investigating for the first ...
Neutron diffraction experiments with hydrogen isotope substitution on aqueous solutions of HCl and H...
Understanding the performance of individual ions in salt solutions and the consequence of ionic hydr...
Pressure perturbation calorimetry (PPC) was used to study the relationship between water and sodium ...
Abstract — The principle of corresponding states is valid in reasonable approximation for ionic flui...
A simple method is proposed for estimating the vapour pressures of aqueous single electrolyte soluti...
Alkali metal cations play vital roles in chemical and biochemical systems. Lithium is widely used in...