Add to ORKG511-515Halogen oxidation of several sym-diarylthioureas (L), viz. , sym-diphenylthiourea (dptu), sym-di-o-tolylthiourea (dottu), sym-di-o-anisidylthiourea (doatu) and sym-di-α-naphthylthiourea (dantu) chromium and molybdenum carbonyls have been studied. The species isolated are heptacoordinated [(L)Mo(CO)4X2], hexacoordinated [(L)Cr(CO)4X]X and [(L)Cr(CO)3X2] (X = Br or I). Mixed ligand molybdenum tricarbonyls, [(bipy)(L)Mo(CO)3] after reaction with bromine or iodine have given [(bipy)Mo(CO)3X2] whereas chlorine displaces both diarylthiourea and CO ligands and the product,[(bipy)MoCl4] has been obtained. However, halogen oxidation of [(bipy)(L)Cr(CO)3] has given [(bipy)CrX2] (X = Cl, Br or 1). The complexes have been identified...
[MoCl(CO)3(η5-C5H5)] on photolysis with allyl or crotyl halides C5H4RX gives Mo(IV) complexes [MoX2(...
The focus of this dissertation centers on the direct on-metal halogenation of trispyrazoyl borate li...
International audienceThe reaction of [ η-C5Me5Mo(CO)3 ]2 with allyl chloride in refluxing THF gives...
Department of Chemistry, University of Gorakhpur, Gorakhpur-273 001 (L-L)(Ph3E)Mo(CO)2 (L-L=o-phen ...
Kölle U, Ding T-zhen, Weber L. Oxidation of chromium, molybdenum, and tungsten sulfur ylide complexe...
The reactions of MoCl5, 1, with small amounts of a series of carbonyl compounds in chlorinated solve...
The reactions of MoCl5, 1, with small amounts of a series of carbonyl compounds in a chlorinated sol...
79-85Reaction of tris(acetonitrile)molybdenumtricarbonyl [Mo(CO)3(CH)CN)3] and tris(acetonitrile)ch...
A number of new adducts of the metal-halogen cluster Mo₆Cl₈⁴⁺ have been prepared and characterized. ...
International audienceThe reactions of molybdenum(0) complexes with I2 have been investigated under ...
Diorganoantimonverbindungen R\(_2\)SbX (R = C\(_6\)H\(_5\) X = S-Organyl, O-Organyl) reagieren mit C...
Under appropriate conditions the reaction of [M(η5-C5Me5)(NO)(CO)2] [M = Mo, (1) or W, (2)] with X2 ...
The molybdenum(II) and tungsten(II) halocarbonyls, [M(CO)4X2]2 (M = Mo, W; X = Cl, Br) react with a ...
Department of Chemistry, S. N. Science Campus, Mahendra Nagar, Mahakali Zone, Nepal Manuscript rece...
The oxidation of [(Cp*Mo)2(μ,η6:η6-P6)] (1) with halogens or halogen sources was investigated. The i...
[MoCl(CO)3(η5-C5H5)] on photolysis with allyl or crotyl halides C5H4RX gives Mo(IV) complexes [MoX2(...
The focus of this dissertation centers on the direct on-metal halogenation of trispyrazoyl borate li...
International audienceThe reaction of [ η-C5Me5Mo(CO)3 ]2 with allyl chloride in refluxing THF gives...
Department of Chemistry, University of Gorakhpur, Gorakhpur-273 001 (L-L)(Ph3E)Mo(CO)2 (L-L=o-phen ...
Kölle U, Ding T-zhen, Weber L. Oxidation of chromium, molybdenum, and tungsten sulfur ylide complexe...
The reactions of MoCl5, 1, with small amounts of a series of carbonyl compounds in chlorinated solve...
The reactions of MoCl5, 1, with small amounts of a series of carbonyl compounds in a chlorinated sol...
79-85Reaction of tris(acetonitrile)molybdenumtricarbonyl [Mo(CO)3(CH)CN)3] and tris(acetonitrile)ch...
A number of new adducts of the metal-halogen cluster Mo₆Cl₈⁴⁺ have been prepared and characterized. ...
International audienceThe reactions of molybdenum(0) complexes with I2 have been investigated under ...
Diorganoantimonverbindungen R\(_2\)SbX (R = C\(_6\)H\(_5\) X = S-Organyl, O-Organyl) reagieren mit C...
Under appropriate conditions the reaction of [M(η5-C5Me5)(NO)(CO)2] [M = Mo, (1) or W, (2)] with X2 ...
The molybdenum(II) and tungsten(II) halocarbonyls, [M(CO)4X2]2 (M = Mo, W; X = Cl, Br) react with a ...
Department of Chemistry, S. N. Science Campus, Mahendra Nagar, Mahakali Zone, Nepal Manuscript rece...
The oxidation of [(Cp*Mo)2(μ,η6:η6-P6)] (1) with halogens or halogen sources was investigated. The i...
[MoCl(CO)3(η5-C5H5)] on photolysis with allyl or crotyl halides C5H4RX gives Mo(IV) complexes [MoX2(...
The focus of this dissertation centers on the direct on-metal halogenation of trispyrazoyl borate li...
International audienceThe reaction of [ η-C5Me5Mo(CO)3 ]2 with allyl chloride in refluxing THF gives...