1263-1265The pKa values of some 14 monobasic organic acids like carboxylates, phenols, etc. are determined in acetonitrile from conductivity measurements. These pKa values are found to be higher than those reported in the aqueous medium on the average by 2.8 (± 1.1) pKa unit. A thermodynamic rationalisation of this observation is provided. It emerges that an acid should be more acidic in water than in acetonitrile as water being more polar than acetonitrile brings about greater ionisation of an acid
For a series of seven unsaturated and seven epoxy di- and tricarboxylic acids, pK(a)(a) values were ...
The acid dissociation constants (pK<sub>a</sub>s) of a number of novel polymerisable vinyl biaryl co...
In this paper, the dissociation constants (pKa) of some nitrogen-containing organic bases (aniline, ...
The dissociation constants of monochloro-and trichloro-acetic acids, aminobenzoic and propionic acid...
A voltammetric method has been developed for the determination of the acid dissociation constant (pK...
Potassium hydrogen phthalate (KHP) is a primary titrimetric standard, and KHP solutions are also use...
The potentiometric titration curves of acids of different types were studied using piperidine and te...
AbstractWe present a simple approach for the calculation of accurate pKa values in water and acetoni...
The COSMO-RS method, a combination of the quantum chemical dielectric continuum solvation model COSM...
983-988The conductivities of oxalic, malonic, succinic, glutaric and adipic acids have been measured...
© 2018 American Chemical Society. The acid dissociation constants (pKa) of four organic acids (formi...
Department of Chemistry, Kalyani University, West Bengal, India. Manuscript received 1 March 1977, ...
For various acids and bases dissociation constants were determined conductimetrically in m-cresol. A...
Chemistry Department, Gujarat University, Ahmedabad-9 Received 20 July 1971; accepted for publicati...
For a series of seven unsaturated and seven epoxy di- and tricarboxylic acids, pK(a)(a) values were ...
For a series of seven unsaturated and seven epoxy di- and tricarboxylic acids, pK(a)(a) values were ...
The acid dissociation constants (pK<sub>a</sub>s) of a number of novel polymerisable vinyl biaryl co...
In this paper, the dissociation constants (pKa) of some nitrogen-containing organic bases (aniline, ...
The dissociation constants of monochloro-and trichloro-acetic acids, aminobenzoic and propionic acid...
A voltammetric method has been developed for the determination of the acid dissociation constant (pK...
Potassium hydrogen phthalate (KHP) is a primary titrimetric standard, and KHP solutions are also use...
The potentiometric titration curves of acids of different types were studied using piperidine and te...
AbstractWe present a simple approach for the calculation of accurate pKa values in water and acetoni...
The COSMO-RS method, a combination of the quantum chemical dielectric continuum solvation model COSM...
983-988The conductivities of oxalic, malonic, succinic, glutaric and adipic acids have been measured...
© 2018 American Chemical Society. The acid dissociation constants (pKa) of four organic acids (formi...
Department of Chemistry, Kalyani University, West Bengal, India. Manuscript received 1 March 1977, ...
For various acids and bases dissociation constants were determined conductimetrically in m-cresol. A...
Chemistry Department, Gujarat University, Ahmedabad-9 Received 20 July 1971; accepted for publicati...
For a series of seven unsaturated and seven epoxy di- and tricarboxylic acids, pK(a)(a) values were ...
For a series of seven unsaturated and seven epoxy di- and tricarboxylic acids, pK(a)(a) values were ...
The acid dissociation constants (pK<sub>a</sub>s) of a number of novel polymerisable vinyl biaryl co...
In this paper, the dissociation constants (pKa) of some nitrogen-containing organic bases (aniline, ...