Infrared absorption spectra for molecular beams of Ne·OCS have been observed with a diode laser for the vibrational transition near 2062 cm -1 correlating with the monomer ν3 mode. The linewidths were ∼150 MHz (FWHM), giving rotationally resolved spectra and allowing the upper and lower vibrational state A, B, and C rotational constants to be determined along with the frequency of the band origin. No broadening in excess of that expected from Doppler effects and laser linewidth was observed, setting a lower limit of 10-9 s on the lifetime of the upper state. Rotational transitions for the vibrational ground state were observed by microwave-infrared double resonance experiments. The ∼150 kHz linewidths in these experiments increased the prec...
Author Institution: Department of Physics and Astronomy, University of Calgary, 2500 University Dr.,...
High resolution rotational spectra were obtained for a several weakly-bound complexes (WBC) and one ...
Spectra of the nonpolar carbonyl sulfide dimer in the region of the OCS \u3bd1 fundamental band were...
Resolved vibration-rotation spectra for Ne·OCS, Ar·OCS and Kr·OCS in the ν3 region of the OCS monome...
[1] S. Grebenev, M. Hartmann, M. Havenith, B. Sartakov, J.P. Toennies, and A.F. Vilesov, J. Chem. Ph...
Author Institution: Physical Chemistry Laboratory, Oxford University; Physical Chemistry Laboratory,...
Infrared laser absorption spectroscopy has been carried out on a molecular beam containing the ArHCC...
The weakly bound van der Waals complex CH\u2084\u2013CO has been observed spectroscopically for the ...
Author Institution: Department of Chemistry, Faculty of ScienceLaser-microwave double resonance (LMD...
The binary complex of rare gas atom and water is an ideal model to study the anisotropic potential e...
Author Institution: Division of Physics, National Research CouncilThe infrared vibration-rotation tr...
Author Institution: Universite de Lille ITheobservation in microwave spectroscopy of rotational tran...
Infrared spectra of OCS\u2013C2H2 and OCS\u2013C2D2 complexes in the region of the C\u2013O stretchi...
Author Institution: Department of Chemistry, University of North CarolinaHigh resolution near infrar...
Infrared absorption spectra are reported for rare-gas-carbon dioxide van der Waals complexes in the ...
Author Institution: Department of Physics and Astronomy, University of Calgary, 2500 University Dr.,...
High resolution rotational spectra were obtained for a several weakly-bound complexes (WBC) and one ...
Spectra of the nonpolar carbonyl sulfide dimer in the region of the OCS \u3bd1 fundamental band were...
Resolved vibration-rotation spectra for Ne·OCS, Ar·OCS and Kr·OCS in the ν3 region of the OCS monome...
[1] S. Grebenev, M. Hartmann, M. Havenith, B. Sartakov, J.P. Toennies, and A.F. Vilesov, J. Chem. Ph...
Author Institution: Physical Chemistry Laboratory, Oxford University; Physical Chemistry Laboratory,...
Infrared laser absorption spectroscopy has been carried out on a molecular beam containing the ArHCC...
The weakly bound van der Waals complex CH\u2084\u2013CO has been observed spectroscopically for the ...
Author Institution: Department of Chemistry, Faculty of ScienceLaser-microwave double resonance (LMD...
The binary complex of rare gas atom and water is an ideal model to study the anisotropic potential e...
Author Institution: Division of Physics, National Research CouncilThe infrared vibration-rotation tr...
Author Institution: Universite de Lille ITheobservation in microwave spectroscopy of rotational tran...
Infrared spectra of OCS\u2013C2H2 and OCS\u2013C2D2 complexes in the region of the C\u2013O stretchi...
Author Institution: Department of Chemistry, University of North CarolinaHigh resolution near infrar...
Infrared absorption spectra are reported for rare-gas-carbon dioxide van der Waals complexes in the ...
Author Institution: Department of Physics and Astronomy, University of Calgary, 2500 University Dr.,...
High resolution rotational spectra were obtained for a several weakly-bound complexes (WBC) and one ...
Spectra of the nonpolar carbonyl sulfide dimer in the region of the OCS \u3bd1 fundamental band were...