The behavior of adsorbed CO at polycrystalline copper surface was investigated by infrared spectroscopy. It was found that the linear adsorbed CO, Cu-COL was a dominant species on copper surface at low CO concentration. Cu-COL was electrochemically converted to bridge bonded CO, Cu-COB at high CO concentration. Increasing the CO surface coverage, θCO will increase the formation of adsorbed bridge bonded CO. N2 purging treatment was used to examine the stability of the adsorbed CO through the evacuation process. The Cu-COB remained intact while Cu-COL was completely removed from the copper surface. It suggests that Cu-COL may involve in a weak bonding to a copper surface such as in a physisorbed interaction, while Cu-COB consists much stron...
Carbon monoxide participates in many copper-catalyzed reactions, which makes CO-induced structural c...
The redox processes occurring on the copper surface in phosphate buffered solution were investigate...
Carbon monoxide adsorbed on Al-promoted Ni and Cu surfaces undergoes facile dissociation at 300 K or...
Oxide-derived copper (OD-Cu) has been shown to favor C2 and C3 products in electrochemical CO reduct...
Surface-adsorbed CO is generally considered a reactive on-pathway intermediate in the aqueous electr...
Using attenuated total reflection (ATR) infrared spectroscopy and ∼10 nm thick, sputtered Cu-films o...
FTIR spectra are reported of CO adsorbed on silica-supported copper catalysts prepared from copper(I...
Adsorption of carbon monoxide at room temperature (0.1–50 Torr) on silica-supported copper oxide was...
1. A.A. Davydov, Infrared Spectroscopy of Adsorbed Species on the Surface of Transition Metal oxides...
The binding energies of (isolated) CO molecules adsorbed at several atomic sites (terrace, step, kin...
Vita.In this work, well-defined bimetallic surfaces have been studied using carbon monoxide adsorpti...
The kinetics of elementary surface processes, intermolecular interactions and stepped surfaces are i...
Understanding the role of the oxidation state of the Cu surface and surface-adsorbed intermediate sp...
Carbon dioxide electroreduction on copper electrode was studied by surface enhanced Raman scattering...
Infrared spectroscopy is used to study the adsorption of carbon monoxide (20°C; 0.1– 100 Torr) on co...
Carbon monoxide participates in many copper-catalyzed reactions, which makes CO-induced structural c...
The redox processes occurring on the copper surface in phosphate buffered solution were investigate...
Carbon monoxide adsorbed on Al-promoted Ni and Cu surfaces undergoes facile dissociation at 300 K or...
Oxide-derived copper (OD-Cu) has been shown to favor C2 and C3 products in electrochemical CO reduct...
Surface-adsorbed CO is generally considered a reactive on-pathway intermediate in the aqueous electr...
Using attenuated total reflection (ATR) infrared spectroscopy and ∼10 nm thick, sputtered Cu-films o...
FTIR spectra are reported of CO adsorbed on silica-supported copper catalysts prepared from copper(I...
Adsorption of carbon monoxide at room temperature (0.1–50 Torr) on silica-supported copper oxide was...
1. A.A. Davydov, Infrared Spectroscopy of Adsorbed Species on the Surface of Transition Metal oxides...
The binding energies of (isolated) CO molecules adsorbed at several atomic sites (terrace, step, kin...
Vita.In this work, well-defined bimetallic surfaces have been studied using carbon monoxide adsorpti...
The kinetics of elementary surface processes, intermolecular interactions and stepped surfaces are i...
Understanding the role of the oxidation state of the Cu surface and surface-adsorbed intermediate sp...
Carbon dioxide electroreduction on copper electrode was studied by surface enhanced Raman scattering...
Infrared spectroscopy is used to study the adsorption of carbon monoxide (20°C; 0.1– 100 Torr) on co...
Carbon monoxide participates in many copper-catalyzed reactions, which makes CO-induced structural c...
The redox processes occurring on the copper surface in phosphate buffered solution were investigate...
Carbon monoxide adsorbed on Al-promoted Ni and Cu surfaces undergoes facile dissociation at 300 K or...