A synthetic route towards the synthesis of TAN1251B was developed utilizing an alkylidene carbene insertion reaction as a key step to construct the quartenary centre. The ?-hydroxylation of the 5,6-spirocyclic enone with iodosobenzene was successful to give a mixture of diastereomer compounds 20 and 21 in 1:1.2 ratios
Research progress towards the total synthesis of A-74528 is described herein. Highlights of the synt...
The insertion reaction of alkylidene carbenes is demonstrated to be an effective method for the synt...
The synthesis and cyclisation of 3-methyl-4-methylene-3-(3-diazo-3-methoxycarbonyl-2-oxopropyl)-1-cy...
This thesis describes studies, which have been realised towards the total syntheses of two natural p...
A regiospecific and stereoselective total synthesis of the trisnorsesquiternene (±)-albene, via a pr...
A regiospecific and stereoselective total synthesis of the trisnorsesquiternene (±)-albene, via a pr...
Abstract: Mild thermolysis of diakyltitanocenes can generate a reactive titanocene alkylidene specie...
Stereoselective 9-step conversions of the ketone 17 into the tricyclic ketone 31 via two similar syn...
The various structural types into which the 'higher terpenes' are divided are defined; recent work o...
The first chapter describes the synthesis of curvulone B featuring a strategy of cross metathesis an...
This thesis describes synthetic studies aimed towards developing a concise synthesis of taxinine, a ...
Key Word Index-Albene; quaternary carbons; Claisen rearrangement; diazo ketone; cyclopropana-tion; r...
The thesis describes the synthesis and application of various alkynones derived from the bis-Weinreb...
The formation of quaternary centers is a formidable challenge. Once these quaternary centers become ...
This thesis describes a total synthesis of the sesquiterpenoid (±)-β-panasinsene (31). Two differe...
Research progress towards the total synthesis of A-74528 is described herein. Highlights of the synt...
The insertion reaction of alkylidene carbenes is demonstrated to be an effective method for the synt...
The synthesis and cyclisation of 3-methyl-4-methylene-3-(3-diazo-3-methoxycarbonyl-2-oxopropyl)-1-cy...
This thesis describes studies, which have been realised towards the total syntheses of two natural p...
A regiospecific and stereoselective total synthesis of the trisnorsesquiternene (±)-albene, via a pr...
A regiospecific and stereoselective total synthesis of the trisnorsesquiternene (±)-albene, via a pr...
Abstract: Mild thermolysis of diakyltitanocenes can generate a reactive titanocene alkylidene specie...
Stereoselective 9-step conversions of the ketone 17 into the tricyclic ketone 31 via two similar syn...
The various structural types into which the 'higher terpenes' are divided are defined; recent work o...
The first chapter describes the synthesis of curvulone B featuring a strategy of cross metathesis an...
This thesis describes synthetic studies aimed towards developing a concise synthesis of taxinine, a ...
Key Word Index-Albene; quaternary carbons; Claisen rearrangement; diazo ketone; cyclopropana-tion; r...
The thesis describes the synthesis and application of various alkynones derived from the bis-Weinreb...
The formation of quaternary centers is a formidable challenge. Once these quaternary centers become ...
This thesis describes a total synthesis of the sesquiterpenoid (±)-β-panasinsene (31). Two differe...
Research progress towards the total synthesis of A-74528 is described herein. Highlights of the synt...
The insertion reaction of alkylidene carbenes is demonstrated to be an effective method for the synt...
The synthesis and cyclisation of 3-methyl-4-methylene-3-(3-diazo-3-methoxycarbonyl-2-oxopropyl)-1-cy...