Entanglement in single-particle systems

We address some of the most commonly raised questions about entanglement, especially with regard to the so-called occupation number entanglement. To answer unambiguously whether entanglement can exist in a one-atom delocalized state, we propose an experiment capable of showing violations of Bell's inequality using only this state and local operations. We review previous discussions for one-photon non-locality and propose a specific experiment for creating one-atom entangled states, showing that the superselection rule of atom number can be overcome. As a by-product, this experiment suggests a means of creating an entangled state of two different chemical species. By comparison with a massless system, we argue that there should be no fundamental objection to such a superposition and its creation may be within reach of present technology. © 2007 The Royal Society