Geochemical characterization of black shales from the Río Mayer Formation (Early Cretaceous), Austral-Magallanes Basin, Argentina: Provenance response during Gondwana break-up

During the Early Cretaceous important changes occurred in South-western Gondwana related to its fragmentation, and South Atlantic Ocean opening. Then, two basins developed in southernmost Patagonia: the Austral-Magallanes Basin and the Rocas Verdes-Magallanes Basin. The Río Mayer Formation corresponds to the initial sedimentary stages of the Austral Basin including black shales, marls and fine-grained sandstones deposited in an outer shelf environment. We studied and sampled three detailed sedimentary logs at Río Guanaco Locality (S 49° 57′ 11?; W 72° 04′ 56″), dividing this unit into three informal sections (lower, middle and upper). Whole rock geochemical analyses were carried out over the three sections with the focus on trace elements, in particular, rare earth elements (REE). While, the lower section of the unit shows an affinity to acid volcanic source areas, the middle and upper sections show an affinity to intermediate source areas. These changes through the Río Mayer Formation can be correlated with the initial magmatic activity hosted in the Southern Patagonian Batholith during the Neocomian. Considering the REE patterns, the lower section of the Río Mayer Formation shows an affinity to the felsic compositions of the Tobífera Formation, while the upper section would be related to the erosion of the Punta Barrosa/Cerro Toro formations of the Rocas Verdes-Magallanes Basin. The clear distinction between the REE patterns of the Río Mayer and Zapata formations is considered evidence of the compartmentalization of these basins during the Early Cretaceous. Finally, the absence of correlation between the geochemistry of the studied unit and the Jurassic volcanic rocks of the Deseado Massif indicates that the north-eastern sector of the basin was not a source area for the Austral Basin, at least during the deposition of the Río Mayer Formation in the study area.Fil: Richiano, Sebastián Miguel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Centro Nacional Patagónico. Instituto Patagónico de Geología y Paleontología; ArgentinaFil: Gómez Peral, Lucia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones Geológicas. Universidad Nacional de La Plata. Facultad de Ciencias Naturales y Museo. Centro de Investigaciones Geológicas; ArgentinaFil: Varela, Augusto Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones Geológicas. Universidad Nacional de La Plata. Facultad de Ciencias Naturales y Museo. Centro de Investigaciones Geológicas; ArgentinaFil: Gómez Dacal, Alejandro Rubén. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Naturales y Museo; ArgentinaFil: Cavarozzi, Claudia Ernestina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones Geológicas. Universidad Nacional de La Plata. Facultad de Ciencias Naturales y Museo. Centro de Investigaciones Geológicas; ArgentinaFil: Poire, Daniel Gustavo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones Geológicas. Universidad Nacional de La Plata. Facultad de Ciencias Naturales y Museo. Centro de Investigaciones Geológicas; Argentin