Add to ORKGBranched allylic CF 3 products are accessible by copper-catalyzed trifluoromethylation of allylsilanes with the Togni reagent I. The silyl group is critical to control the outcome of this reaction because in its absence, a product of addition between the alkene and the Togni reagent is formed preferentially. The reaction is inhibited with 2,2,6,6-tetramethyl-1- piperidinyloxy (TEMPO) and is likely to operate via multiple reaction pathways. Copyright © 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim
An efficient method for the copper-catalyzed trifluoromethylation of terminal alkenes with an electr...
A method has been developed for the synthesis of α-trifluoromethyl ketones via the Cu-catalyzed trif...
This thesis is concerned with the development of methodology for late-stage trifluoromethylation of ...
Electrophilic trifluoromethylthiolation of allylsilanes and silyl enol ethers with trifluoromethanes...
An efficient copper-catalyzed allylic trifluoromethylation reaction has been developed. This reactio...
A new catalytic method to access allylic secondary CF<sub>3</sub> products is described. These react...
A new catalytic method to access allylic secondary CF3 products is described. These reactions use th...
Copper-mediated trifluoromethylation of allylic chlorides and trifluoroacetates was performed using ...
The first part of this thesis presents a novel approach for synthesising enantioenriched cyclic ally...
A novel copper-catalyzed intermolecular trifluoromethylarylation of alkenes is developed using l...
The first part of this thesis presents a novel approach for synthesising enantioenriched cyclic ally...
An efficient C(sp<sup>3</sup>)–CF<sub>3</sub> bond-forming reaction via Cu-catalyzed oxidative trifl...
The introduction of trifluoromethyl groups into organic molecules has attracted great attention in t...
International audienceMild and practical: Trifluoromethylation of (hetero)aromatic aldehyde N,N-dial...
Soft reaction conditions, particularly important in total synthesis, have dragged many researchers i...
An efficient method for the copper-catalyzed trifluoromethylation of terminal alkenes with an electr...
A method has been developed for the synthesis of α-trifluoromethyl ketones via the Cu-catalyzed trif...
This thesis is concerned with the development of methodology for late-stage trifluoromethylation of ...
Electrophilic trifluoromethylthiolation of allylsilanes and silyl enol ethers with trifluoromethanes...
An efficient copper-catalyzed allylic trifluoromethylation reaction has been developed. This reactio...
A new catalytic method to access allylic secondary CF<sub>3</sub> products is described. These react...
A new catalytic method to access allylic secondary CF3 products is described. These reactions use th...
Copper-mediated trifluoromethylation of allylic chlorides and trifluoroacetates was performed using ...
The first part of this thesis presents a novel approach for synthesising enantioenriched cyclic ally...
A novel copper-catalyzed intermolecular trifluoromethylarylation of alkenes is developed using l...
The first part of this thesis presents a novel approach for synthesising enantioenriched cyclic ally...
An efficient C(sp<sup>3</sup>)–CF<sub>3</sub> bond-forming reaction via Cu-catalyzed oxidative trifl...
The introduction of trifluoromethyl groups into organic molecules has attracted great attention in t...
International audienceMild and practical: Trifluoromethylation of (hetero)aromatic aldehyde N,N-dial...
Soft reaction conditions, particularly important in total synthesis, have dragged many researchers i...
An efficient method for the copper-catalyzed trifluoromethylation of terminal alkenes with an electr...
A method has been developed for the synthesis of α-trifluoromethyl ketones via the Cu-catalyzed trif...
This thesis is concerned with the development of methodology for late-stage trifluoromethylation of ...