We have performed scattering experiments on dilute solutions of polydisperse and fractionated sol phases obtained in a gelation process. The comparison of the structure factors allows one to separate size polydispersity effects and conformational properties of the branched species. Our results show that their behavior in solution agrees rather well with the one expected for swollen percolation clusters.Nous avons effectué des expériences de diffusion de rayonnement sur des solutions diluées de phases sol produites lors d'une réaction de gélification. La comparaison des facteurs de structure mesurés sur des échantillons fractionnés ou non fractionnés permet de séparer les effets de dispersion en tailles et les propriétés conformationnelles d...
The gelification process by polycondensation leading to self similar clusters of polyurethane is stu...
We consider the time dependent scattered intensity S(q, t ) by a dilute solution of randomly branche...
We present an analysis of the impact of structural disorder on the static scattering function of f-a...
Small angle neutron scattering experiments were performed on Polyurethane branched polymers syntheti...
Small angle neutron scattering experiments were performed on Polyurethane branched polymers syntheti...
Small angle neutron scattering experiments were performed on Polyurethane branched polymers syntheti...
Experimentally relevant properties of a sol diluted in a good solvent are studied Dilution leaves th...
We study the conformation of randomly branched, monodispersed polymers both in dilute and concentrat...
We study the conformation of randomly branched, monodispersed polymers both in dilute and concentrat...
étudiées. La dilution laisse la distribution en masse inchangée mais conduit à un gonflement de chaq...
We study the static properties of solutions of randomly branched poly(methyl methacrylate) (PMMA) ob...
Static and dynamical properties of randomly branched polymers in dilute solutions were investigated ...
The swelling of percolation clusters as models for gelling branched polymers is analyzed by using a ...
Static and dynamical properties of randomly branched polymers in dilute solutions were investigated ...
The gelification process by polycondensation leading to self similar clusters of polyurethane is stu...
The gelification process by polycondensation leading to self similar clusters of polyurethane is stu...
We consider the time dependent scattered intensity S(q, t ) by a dilute solution of randomly branche...
We present an analysis of the impact of structural disorder on the static scattering function of f-a...
Small angle neutron scattering experiments were performed on Polyurethane branched polymers syntheti...
Small angle neutron scattering experiments were performed on Polyurethane branched polymers syntheti...
Small angle neutron scattering experiments were performed on Polyurethane branched polymers syntheti...
Experimentally relevant properties of a sol diluted in a good solvent are studied Dilution leaves th...
We study the conformation of randomly branched, monodispersed polymers both in dilute and concentrat...
We study the conformation of randomly branched, monodispersed polymers both in dilute and concentrat...
étudiées. La dilution laisse la distribution en masse inchangée mais conduit à un gonflement de chaq...
We study the static properties of solutions of randomly branched poly(methyl methacrylate) (PMMA) ob...
Static and dynamical properties of randomly branched polymers in dilute solutions were investigated ...
The swelling of percolation clusters as models for gelling branched polymers is analyzed by using a ...
Static and dynamical properties of randomly branched polymers in dilute solutions were investigated ...
The gelification process by polycondensation leading to self similar clusters of polyurethane is stu...
The gelification process by polycondensation leading to self similar clusters of polyurethane is stu...
We consider the time dependent scattered intensity S(q, t ) by a dilute solution of randomly branche...
We present an analysis of the impact of structural disorder on the static scattering function of f-a...