The photochemical reaction of Ru(CO)(3)(L)(2), where L = PPh(3), PMe(3), PCy(3) and P(p-tolyl)(3) with parahydrogen (p-H(2)) has been studied by in-situ NMR spectroscopy and shown to result in two competing processes. The first of these involves loss of CO and results in the formation of the cis-cis-trans-L isomer of Ru(CO)(2)(L)(2)(H)(2), while in the second, a single photon induces loss of both CO and L and leads to the formation of cis-cis-cis Ru(CO)(2)(L)(2)(H)(2) and Ru(CO)(2)(L)(solvent)(H)(2) where solvent = toluene, THF and pyridine (py). In the case of L = PPh(3), cis-cis-trans-L Ru(CO)(2)(L)(2)(H)(2) is shown to be an effective hydrogenation catalyst with rate limiting phosphine dissociation proceeding at a rate of 2.2 s(-1) in py...
ABSTRACT Most metal dihydride complexes with cis hydride ligands undergo photochemical reductive eli...
The complexes M(CO)2(PPh3)3 (I, M = Fe; II, M = Ru) readily react with H2 at room temperature and at...
The reactions of RhCl(PBz3)3 with H2 and pyridine or 4-methylpyridine yield RhCl(H)2(PBz3)2(py) and ...
The photochemical reaction of Ru(CO)(3)(L)(2), where L = PPh(3), PMe(3), PCy(3) and P(p-tolyl)(3) wi...
International audienceThe photochemical reaction of Ru(CO)3(L)2, where L = PPh3, PMe3, PCy3 and P(p-...
The thermal and photochemical reactivity of Ru(CO)3(dpae) (1) and Ru(CO)2(dpae)(PPh3) (2) towards H2...
International audienceThe synthesis, characterisation and thermal and photochemical reactivity of Ru...
International audienceThe synthesis, characterisation and thermal and photochemical reactivity of Ru...
International audienceThe synthesis, characterisation and thermal and photochemical reactivity of Ru...
The photochemical reaction of Ru(CO)(3)(dppe) and Fe(CO)(3)(dppe)(dppe = Ph(2)PCH(2)CH(2)PPh(2)) wit...
International audienceThe photochemical reaction of Ru(CO)3(dppe) and Fe(CO)3(dppe) (dppe = Ph2PCH2C...
The photochemistry of Ru(H)(CO)(PPh) (1) has been reinvestigated employing laser and conventional li...
The reactivity of the cluster family [Ru3(CO)12-x(L)x] (in which L=PMe3, PMe2Ph, PPh3 and PCy3, x=1-...
The activity of novel ruthenium-hydride complexes RuHCl(CO)(IMes)(PPh 3) and RuHCl(CO)(H2IMes)(PPh3)...
The known ruthenium pincer complex RuCl(eta3-dcpx)(PPh 3) (7) (PCP = eta3-2,6-(PCy2CH 2)2C6H3) was t...
ABSTRACT Most metal dihydride complexes with cis hydride ligands undergo photochemical reductive eli...
The complexes M(CO)2(PPh3)3 (I, M = Fe; II, M = Ru) readily react with H2 at room temperature and at...
The reactions of RhCl(PBz3)3 with H2 and pyridine or 4-methylpyridine yield RhCl(H)2(PBz3)2(py) and ...
The photochemical reaction of Ru(CO)(3)(L)(2), where L = PPh(3), PMe(3), PCy(3) and P(p-tolyl)(3) wi...
International audienceThe photochemical reaction of Ru(CO)3(L)2, where L = PPh3, PMe3, PCy3 and P(p-...
The thermal and photochemical reactivity of Ru(CO)3(dpae) (1) and Ru(CO)2(dpae)(PPh3) (2) towards H2...
International audienceThe synthesis, characterisation and thermal and photochemical reactivity of Ru...
International audienceThe synthesis, characterisation and thermal and photochemical reactivity of Ru...
International audienceThe synthesis, characterisation and thermal and photochemical reactivity of Ru...
The photochemical reaction of Ru(CO)(3)(dppe) and Fe(CO)(3)(dppe)(dppe = Ph(2)PCH(2)CH(2)PPh(2)) wit...
International audienceThe photochemical reaction of Ru(CO)3(dppe) and Fe(CO)3(dppe) (dppe = Ph2PCH2C...
The photochemistry of Ru(H)(CO)(PPh) (1) has been reinvestigated employing laser and conventional li...
The reactivity of the cluster family [Ru3(CO)12-x(L)x] (in which L=PMe3, PMe2Ph, PPh3 and PCy3, x=1-...
The activity of novel ruthenium-hydride complexes RuHCl(CO)(IMes)(PPh 3) and RuHCl(CO)(H2IMes)(PPh3)...
The known ruthenium pincer complex RuCl(eta3-dcpx)(PPh 3) (7) (PCP = eta3-2,6-(PCy2CH 2)2C6H3) was t...
ABSTRACT Most metal dihydride complexes with cis hydride ligands undergo photochemical reductive eli...
The complexes M(CO)2(PPh3)3 (I, M = Fe; II, M = Ru) readily react with H2 at room temperature and at...
The reactions of RhCl(PBz3)3 with H2 and pyridine or 4-methylpyridine yield RhCl(H)2(PBz3)2(py) and ...