We show that, by combining diffusion and viscosity measurements for a flexible polymer in the dilute regime, it is possible to study the variation of the radius of gyration RG with the number of monomers N. The crossover phenomenon is observed around a critical value Nc, together with the expected power laws RG ∝ N ν for N ≷ Nc.Pour un polymère flexible en solution diluée, nous montrons qu'il est possible, à partir de mesures de diffusion et de viscosité, d'étudier les variations du rayon de giration RG avec le nombre de monomères N. On met ainsi en évidence le phénomène de crossover au voisinage d'un nombre critique Nc, et les lois de variation R G ∝ Nν prévues théoriquement pour N ≷ Nc
Experimentally relevant properties of a sol diluted in a good solvent are studied Dilution leaves th...
We study the conformation of randomly branched, monodispersed polymers both in dilute and concentrat...
Ce manuscrit présente les résultats d'expériences illustrant différentes manifestations de la présen...
We analyse the dynamical properties of dilute Polymer solutions by using scaling arguments. To this ...
We develop a crossover theory for dilute polymer solutions, analogous to crossover theories for crit...
Rheological and diffusional properties of a polymer theta-solution are considered on the basis of no...
The viscosimetric behaviour of eleven polymer-solvent systems is analysed in order to determine the ...
It is shown that for a polymer in a dilute solution, the hydrodynamic radius RH and the radius of gy...
It is shown that the cross-over concentration between dilute and semi-dilute solutions is the same f...
A theoretical model, recently introduced to describe the dynamics of reversibly breakable polymer ch...
We study the swelling of one very large molecule made of N monomers in a mixture of a good solvent a...
We study and model the linear viscoelastic properties of several entangled semi-dilute and concentra...
It is shown that the dynamical properties of long polymers made of N links, in solutions, converge m...
Due to their unique topology of having no chain ends, dilute solutions of ring polymers exhibit beha...
The apparent viscosity of dilute polymer solutions in non-inertial flows through channels consisting...
Experimentally relevant properties of a sol diluted in a good solvent are studied Dilution leaves th...
We study the conformation of randomly branched, monodispersed polymers both in dilute and concentrat...
Ce manuscrit présente les résultats d'expériences illustrant différentes manifestations de la présen...
We analyse the dynamical properties of dilute Polymer solutions by using scaling arguments. To this ...
We develop a crossover theory for dilute polymer solutions, analogous to crossover theories for crit...
Rheological and diffusional properties of a polymer theta-solution are considered on the basis of no...
The viscosimetric behaviour of eleven polymer-solvent systems is analysed in order to determine the ...
It is shown that for a polymer in a dilute solution, the hydrodynamic radius RH and the radius of gy...
It is shown that the cross-over concentration between dilute and semi-dilute solutions is the same f...
A theoretical model, recently introduced to describe the dynamics of reversibly breakable polymer ch...
We study the swelling of one very large molecule made of N monomers in a mixture of a good solvent a...
We study and model the linear viscoelastic properties of several entangled semi-dilute and concentra...
It is shown that the dynamical properties of long polymers made of N links, in solutions, converge m...
Due to their unique topology of having no chain ends, dilute solutions of ring polymers exhibit beha...
The apparent viscosity of dilute polymer solutions in non-inertial flows through channels consisting...
Experimentally relevant properties of a sol diluted in a good solvent are studied Dilution leaves th...
We study the conformation of randomly branched, monodispersed polymers both in dilute and concentrat...
Ce manuscrit présente les résultats d'expériences illustrant différentes manifestations de la présen...