CHEMICAL EFFECTS ON K-X-RAY SPECTRUM

Chemical effects on K-x-ray spectrum have been studied both experimentally and theoretically. The K-x-ray spectra of various chemical compounds of Mn and Cr were measured with a double crystal spectrometer with high energy resolution. The theoretical calculations of the K-x-ray energies and intensities were made by the use of the discrete-variational Xα, moleculer orbital method. The experimental spectra are compared with the calculated ones and the dependence of the spectrum and the Kβ /Kα x-ray intensity ratios on the chemical form of the compounds is descussed