Amine for it! A cationic rhodium catalyst, which was assembled insitu from commercial components, promoted the reaction of a range of simple 2-aminobenzaldehydes with terminal and internal alkynes in a series of intermolecular hydroacylation reactions. The products of this reaction, amino-substituted enones, were efficiently converted into the corresponding dihydro-4-quinolones. © 2013 The Authors. Published by Wiley-VCH Verlag GmbH and Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited
The described in this thesis is primarily concerned with the development of Rhhydroacylation based a...
Cross-couplings that proceed via C–H bond activation streamline the synthesis of complex molecules. ...
The pathway for the combination of enones and beta-S-substituted aldehydes using Rh-catalysis can be...
An enamine-controlled hydroacylation of alkynes using a rhodium(I)/dppe catalyst system is described...
This thesis documents the development of two new rhodium(I)-catalysed methodologies. The first shows...
We show that readily available α‐amidoaldehydes are effective substrates for intermolecular Rh‐catal...
We show that readily available α‐amidoaldehydes are effective substrates for intermolecular Rh‐catal...
The Rh-catalyzed hydroacylative union of aldehydes and o-alkynyl anilines leads to 2-aminophenyl en...
The work compiled in this thesis documents the development of new methodologies towards the synthesi...
The work described in this thesis documents the development of new rhodium(I)-catalysed methodologie...
This thesis, submitted for the degree of Doctor of Philosophy in Organic Chemistry, documents new m...
This work describes the extension of rhodium-catalysed intermolecular hydroacylation to encompass so...
Readily available β-carbonyl-substituted aldehydes are shown to be exceptional substrates for Rh-cat...
Chapter 1 – Introduction: The concept of rhodium-catalysed intermolecular hydroacylation is introduc...
This thesis discloses the uses and development of rhodium(I) catalysis within intermolecular hydroac...
The described in this thesis is primarily concerned with the development of Rhhydroacylation based a...
Cross-couplings that proceed via C–H bond activation streamline the synthesis of complex molecules. ...
The pathway for the combination of enones and beta-S-substituted aldehydes using Rh-catalysis can be...
An enamine-controlled hydroacylation of alkynes using a rhodium(I)/dppe catalyst system is described...
This thesis documents the development of two new rhodium(I)-catalysed methodologies. The first shows...
We show that readily available α‐amidoaldehydes are effective substrates for intermolecular Rh‐catal...
We show that readily available α‐amidoaldehydes are effective substrates for intermolecular Rh‐catal...
The Rh-catalyzed hydroacylative union of aldehydes and o-alkynyl anilines leads to 2-aminophenyl en...
The work compiled in this thesis documents the development of new methodologies towards the synthesi...
The work described in this thesis documents the development of new rhodium(I)-catalysed methodologie...
This thesis, submitted for the degree of Doctor of Philosophy in Organic Chemistry, documents new m...
This work describes the extension of rhodium-catalysed intermolecular hydroacylation to encompass so...
Readily available β-carbonyl-substituted aldehydes are shown to be exceptional substrates for Rh-cat...
Chapter 1 – Introduction: The concept of rhodium-catalysed intermolecular hydroacylation is introduc...
This thesis discloses the uses and development of rhodium(I) catalysis within intermolecular hydroac...
The described in this thesis is primarily concerned with the development of Rhhydroacylation based a...
Cross-couplings that proceed via C–H bond activation streamline the synthesis of complex molecules. ...
The pathway for the combination of enones and beta-S-substituted aldehydes using Rh-catalysis can be...