Aromatic acylsilanes [Ar-CO-SiMe3; Ar = C6H5,4-ClC6H4, 2-, 3- and 4-OMeC6H4, 3,4-(OMe)2C6H3 and 3,4-OCH2OC6H3] were reduced by baker's yeast to optically active a-silyl alcohols in 20-70% yield and 43-88% ee. Comments are made on the influence of silicon in this bioreduction reaction. © The Royal Society of Chemistry 1999.2131333137Fleming, I., A. Barbero and D. Walter, Chem. Rev., , 1997, 97, 2063Chan, T.H., And D. Wang, Client. Rev., , 1992, 92, 995Crump, R.A., I. Fleming, J. H. M. Hill, D. Parker, N. L. Reddy and D. Waterson,./ Chem. Soc., Perkin Trans, , . /, 1992, 3277Bassindale, A.R., A. G. Brook, P. F. Jones and J. M. Lennon, Can. J. Chem., , 1975, 53, 332Buynak, J.D., J. B. Strikland, T. Hurd and A. Pan, J. Chem. Soc., Chem. Commun....
International audienceSilyl formates are investigated for the first time as surrogates of hydrosilan...
Stereocontrolled addition of alk-1-enylmetal reagents to the chiral (alkoxymethyl)-substituted acyls...
The anionic ring-opening polymerization of cyclosiloxanes is one important route for synthesizing po...
From MDPI via Jisc Publications RouterHistory: accepted 2021-07-20, pub-electronic 2021-07-22Publica...
Thirty strains of microorganisms (bacteria, yeasts, fungi and green algae) were tested as resting fr...
Thesis advisor: Marc L. SnapperA survey of silicon-based reactions and potential for Lewis base cata...
The highly enantioselective addition of Grignard reagents to acylsilanes is catalyzed by copper diph...
The following short review summarizes the results we achieved with the investigation of chiral silic...
Potassium permanganate supported onto alumina in hexane-water is a good oxidizing agent to convert α...
The trimethylsilylalkyl acetoacetates 1 b and 2 b as well as their carba analogues 1 a and 2 a have ...
The synthesis of the optically active alkoxymethyl-substituted acetylsilanes (+)-3 and (−)-b was ach...
The direct depolymerization of SiO2 to distillable alkoxysilanes has been explored repeatedly withou...
The first part of this thesis studied the capacity of amino acids and enzymes to catalyze the hydrol...
The bioreduction of α-methyleneketones, R 1C(=O)C(=CH 2)R 2 (R 1 = Me, Et, Pr, iso-Bu, Ph, CH 2CH 2P...
The work contained herein focuses on the methodology and design of new reactions for the production ...
International audienceSilyl formates are investigated for the first time as surrogates of hydrosilan...
Stereocontrolled addition of alk-1-enylmetal reagents to the chiral (alkoxymethyl)-substituted acyls...
The anionic ring-opening polymerization of cyclosiloxanes is one important route for synthesizing po...
From MDPI via Jisc Publications RouterHistory: accepted 2021-07-20, pub-electronic 2021-07-22Publica...
Thirty strains of microorganisms (bacteria, yeasts, fungi and green algae) were tested as resting fr...
Thesis advisor: Marc L. SnapperA survey of silicon-based reactions and potential for Lewis base cata...
The highly enantioselective addition of Grignard reagents to acylsilanes is catalyzed by copper diph...
The following short review summarizes the results we achieved with the investigation of chiral silic...
Potassium permanganate supported onto alumina in hexane-water is a good oxidizing agent to convert α...
The trimethylsilylalkyl acetoacetates 1 b and 2 b as well as their carba analogues 1 a and 2 a have ...
The synthesis of the optically active alkoxymethyl-substituted acetylsilanes (+)-3 and (−)-b was ach...
The direct depolymerization of SiO2 to distillable alkoxysilanes has been explored repeatedly withou...
The first part of this thesis studied the capacity of amino acids and enzymes to catalyze the hydrol...
The bioreduction of α-methyleneketones, R 1C(=O)C(=CH 2)R 2 (R 1 = Me, Et, Pr, iso-Bu, Ph, CH 2CH 2P...
The work contained herein focuses on the methodology and design of new reactions for the production ...
International audienceSilyl formates are investigated for the first time as surrogates of hydrosilan...
Stereocontrolled addition of alk-1-enylmetal reagents to the chiral (alkoxymethyl)-substituted acyls...
The anionic ring-opening polymerization of cyclosiloxanes is one important route for synthesizing po...