On passe en revue quelques progrès marquants en mécanique statistique des solutions ioniques. L'accent sera mis sur les modèles qui tiennent compte explicitement de la nature moléculaire du solvant polaire dans le calcul des propriétés thermodynamiques, structurales et diélectriques de solutions concentrées d'électrolytes simples.A review is given of some recent progress in the statistical mechanics of ionic solutions. Special emphasis is laid on simple models which take explicit account of the discrete molecular nature of the polar solvent to predict thermodynamic, structural and dielectric properties of concentrated solutions of simple electrolytes
International audienceThe dielectric constant of ionic solutions is known to reduce with increasing ...
Abstract — The principle of corresponding states is valid in reasonable approximation for ionic flui...
The stepwise solvation-equilibrium model of Stokes and Robinson is used for a description of departu...
The theoretical and simulation methods of statistical thermodynamics aim to develope a relationship ...
In the past, studies of electrolyte solutions have generally treated the solvent only as a dielectri...
International audienceIn their seminal paper of 1923, Debye and Hückel provided the first appropriat...
An improved formulation of the extension of the statistical associating fluid theory for potentials ...
Continuum solvent models of electrolyte solutions are extremely useful. However, before we can use t...
International audienceThe development of simple, primitive model descriptions for electrolyte soluti...
Continuum solvent models of electrolyte solutions are extremely useful. However, before we can use t...
A new combination of the non-random two liq. (NRTL) model with the mean spherical approxn. (MSA) is ...
In this report, a molecular Debye-Hückel theory for ionic fluids is developed. Starting from the mac...
One of the purposes of this paper is to assess the degree of applicability of the nonlinear Poisson-...
Knowledge of the activity coefficients of solutes under temperature and pressure ranges of interest ...
Ion specific effects are common in colloidal and biological systems. Bubble lifetime before coalesce...
International audienceThe dielectric constant of ionic solutions is known to reduce with increasing ...
Abstract — The principle of corresponding states is valid in reasonable approximation for ionic flui...
The stepwise solvation-equilibrium model of Stokes and Robinson is used for a description of departu...
The theoretical and simulation methods of statistical thermodynamics aim to develope a relationship ...
In the past, studies of electrolyte solutions have generally treated the solvent only as a dielectri...
International audienceIn their seminal paper of 1923, Debye and Hückel provided the first appropriat...
An improved formulation of the extension of the statistical associating fluid theory for potentials ...
Continuum solvent models of electrolyte solutions are extremely useful. However, before we can use t...
International audienceThe development of simple, primitive model descriptions for electrolyte soluti...
Continuum solvent models of electrolyte solutions are extremely useful. However, before we can use t...
A new combination of the non-random two liq. (NRTL) model with the mean spherical approxn. (MSA) is ...
In this report, a molecular Debye-Hückel theory for ionic fluids is developed. Starting from the mac...
One of the purposes of this paper is to assess the degree of applicability of the nonlinear Poisson-...
Knowledge of the activity coefficients of solutes under temperature and pressure ranges of interest ...
Ion specific effects are common in colloidal and biological systems. Bubble lifetime before coalesce...
International audienceThe dielectric constant of ionic solutions is known to reduce with increasing ...
Abstract — The principle of corresponding states is valid in reasonable approximation for ionic flui...
The stepwise solvation-equilibrium model of Stokes and Robinson is used for a description of departu...