Expansion of agriculture over ecosystem areas is widely recognized as one of the most significant human alterations to the global environment over the last century. Although food and fiber production are essential ecosystem services (ES) to humankind, the clearing of forests for agricultural use is associated with changes in land cover which affect a wide range of ES at local, regional and global scales. Considering the importance of climate change, freshwater scarcity, soil erosion and other environmental issues, this paper aims to simulate the impact of land-use change on the ecosystem services related to water and carbon biogeochemical processes. The system under study is the Taquarizinho river basin, located in the eastern region of Mat...