Aims. Permittivity measurements on porous samples of volcanic origin have been performed in the 0.05–190 GHz range under laboratory conditions in support of the Rosetta mission to comet 67P/Churyumov–Gerasimenko, specifically with the MIRO radiometric experiment and CONSERT radar experiment. Methods. The samples were split into several subsamples with different size ranges covering a few μm to 500 μm. Bulk densities of the subsamples were estimated to be in the 800 to 1500 kg/m3 range. The porosities were in the range of 48% to 65%. From 50 MHz to 6 GHz and at 190 GHz, permittivity has been determined with a coaxial cell and with a quasi-optical bench, respectively. Results. Without taking into account the volume-scattering ...