Predicting The Claisen Rearrangement Regioselectivity Of Allylindanyl And Allyltetrahydronaphthalenyl Ether Derivatives By 1h Nmr Experiments

The regioselectivity of the Claisen rearrangement of allylindanyl and allyltetrahydronaphthalenyl ether derivatives can be predicted by conformational preference detected by 1H NMR NOE difference spectra and T1 measurements. Copyright © 2000 John Wiley & Sons, Ltd.3811970974Koike, L., Rebouças, L.M.C., Fdeam, R., Marsaioli, A.J., Richnow, H.H., Michaelis, W., (1992) Org. Geochem., 18, p. 851Lopes, J.A.D., Neto, E.V.S., Mello, M.R., Koike, L., Marsaioli, A.J., Fdeam, R., (1999) Chem. Geol., 1, p. 158Nascimento, L.R., Rebouças, L.M.C., Koike, L., Fdeam, R., Soldan, A.L., Cerqueira, J.R., Marsaioli, A.J., (1999) Org. Geochem., 30, p. 1175Aviyente, V., Yoo, H.Y., Houk, K.N., (1997) J. Org. Chem., 62, p. 6121Yamabe, S., Okumoto, S., Hayashi, T., (1996) J. Org. Chem., 61, p. 6218Ganem, B., (1996) Angew. Chem., Int. Ed. Engl., 35, p. 936Hammond, G.S., (1955) J. Am. Chem. Soc., 77, p. 334Kruse, L.I., DeBrosse, C.W., Kruse, C.H., (1985) J. Am. Chem. Soc., 107, p. 5435White, W.N., Slater, C.D., (1961) J. Org. Chem., 26, p. 3631Lauer, W.M., Doldouras, G.A., Hileman, R.E., Liepins, R., (1961) J. Org. Chem., 26, p. 478